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2. A new optical-based technique for real-time measurements of mineral dust concentration in PM10 using a virtual impactorLuka Drinovec, Jean Sciare, IASONAS STAVROULAS, Spiros Bezantakos, Michael Pikridas, FLORIN UNGA, Chrysanthos Savvides, Bojana Višnjić, Maja Remškar, Griša Močnik, 2020, original scientific article Abstract: Atmospheric mineral dust influences Earth’s radiative
budget, cloud formation, and lifetime; has adverse
health effects; and affects air quality through the increase of
regulatory PM10 concentrations, making its real-time quantification
in the atmosphere of strategic importance. Only
few near-real-time techniques can discriminate dust aerosol
in PM10 samples and they are based on the dust chemical
composition. The online determination of mineral dust using
aerosol absorption photometers offers an interesting and
competitive alternative but remains a difficult task to achieve.
This is particularly challenging when dust is mixed with
black carbon, which features a much higher mass absorption
cross section. We build on previous work using filter photometers
and present here for the first time a highly timeresolved
online technique for quantification of mineral dust
concentration by coupling a high-flow virtual impactor (VI)
sampler that concentrates coarse particles with an aerosol absorption
photometer (Aethalometer, model AE33). The absorption
of concentrated dust particles is obtained by subtracting
the absorption of the submicron (PM1) aerosol fraction
from the absorption of the virtual impactor sample (VIPM1
method). This real-time method for detecting desert
dust was tested in the field for a period of 2 months (April and
May 2016) at a regional background site of Cyprus, in the
Eastern Mediterranean. Several intense desert mineral dust
events were observed during the field campaign with dust
concentration in PM10 up to 45 μgm Keywords: aerosol absorption, mineral dust, on-line detection, air quality Published in RUNG: 20.07.2020; Views: 2751; Downloads: 0 This document has many files! More... |
3. Za glavo in srcem : motiviranje za branje v projektih Leo, leo in špasnka vas v letu 2018/2019Barbara Pregelj, Tilka Jamnik, Petra Mikeln, Bojana Tomc, Darja Cekin, Kaja Dragoljević, Polona Konjedic, 2018, professional monograph Keywords: motiviranje za branje, strategije, M. Sarto, recepcija, evalvacija Published in RUNG: 24.01.2019; Views: 4289; Downloads: 134 Full text (6,35 MB) |
4. Removal of manganese in batch and fluidized bed systems using beads of zeolite a as adsorbentMina Jovanovic, Iztok Arčon, Janez Kovač, Nataša Novak Tušar, Bojana Obradovic, Nevenka Rajić, 2016, original scientific article Abstract: In this study the uptake capacity of Mn(II) ions by zeolite A beads was investigated for different initial Mn concentration (100e400 mg Mn dm^-3) in batch mode at 25e55 C. The obtained adsorption capacity varying from 30 to 50 mg Mn g^-1 demonstrated a high affinity of zeolite A towards Mn(II) present in solutions. Kinetic studies indicated the intra-particle diffusion as the rate limiting step up to 45 C with apparent diffusivities in the range (1.2e2.0) x 10^-13 m2 s^-1 and the activation energy of 21.9 kJ mol^-1, which implies strong interactions between the zeolite A and Mn ions. At 55 C ion-exchange became the rate limiting step. The adsorption isotherms were studied at 25 C showing that the Mn adsorption is the best described by the Langmuir model suggesting a homogenous zeolite surface. XPS analysis of the Mnloaded beads showed that there is no surface accumulation of Mn but an almost uniform Mn distribution inside zeolite A, whereas XANES and EXAFS suggested that the adsorption of Mn(II) was followed by the Mn(II) oxidation and oxide formation. Regeneration of the spent zeolite was examined in 8 adsorption/desorption cycles by a chelating Na2EDTA in a fluidized column. It has been found that zeolite A beads could be reused for at least 4 cycles with satisfactory Mn(II) adsorption efficiencies of about 70%. Keywords: Zeolite A
Manganese
Adsorption kinetics
EXAFS/XANES
XPS Published in RUNG: 01.04.2016; Views: 5269; Downloads: 0 This document has many files! More... |