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1.
A novel multi-functional thiophene-based organic cation as passivation, crystalline orientation, and organic spacer agent for low-dimensional 3D/1D perovskite solar cells
Ali Semerci, Ali Buyruk, Saim Emin, Rik Hooijer, Daniela Kovacheva, Peter Mayer, Manuel A. Reus, Dominic Blätte, Marcella Günther, Nicolai F. Hartmann, 2023, original scientific article

Abstract: Recently, the mixed-dimensional (3D/2D or 3D/1D) perovskite solar cellsusing small organic spacers have attracted interest due to their outstandinglong-term stability. Here, a new type of thiophene-based organic cation2-(thiophene-2yl-)pyridine-1-ium iodide (ThPyI), which is used to fabricatemixed-dimensional 3D/1D perovskite solar cells, is presented. TheThPyI-based 1D perovskitoid is applied as a passivator on top of a 3D methylammonium lead iodide (MAPI) to fabricate surface-passivated 3D/1Dperovskite films or added alone into the 3D perovskite precursor to generatebulk-passivated 3D MAPI. The 1D perovskitoid acts as a passivating agent atthe grain boundaries of surface-passivated 3D/1D, which improves the powerconversion efficiency (PCE) of the solar cells. Grazing incidence wide-angleX-ray scattering (GIWAXS) studies confirm that ThPyI triggers the preferentialorientation of the bulk MAPI slabs, which is essential to enhance chargetransport. Champion bulk-passivated 3D and surface-passivated 3D/1Ddevices yield 14.10% and 19.60% PCE, respectively. The bulk-passivated 3Doffers favorable stability, with 84% PCE retained after 2000 h withoutencapsulation. This study brings a new perspective to the design of organicspacers having a different binding motif and a passivation strategy to mitigatethe impact of defects in hybrid 3D/1D perovskite solar cells.A. Semerci, A. Buyruk, R. Hooijer, P. Mayer, D. Blätte, M. Günther, T. Bein,T. AmeriDepartment of Chemistry and Center for NanoScience (CeNS)Ludwig-Maximilians-Universität MünchenButenandtstrasse 5–13 (E), 81377 Munich, GermanyE-mail:tayebeh.ameri@ed.ac.ukS.EminMaterialsResearchLaboratoryUniversityofNovaGoricaVipavska13c,Ajdovšˇcina5270,SloveniaThe ORCID identification number(s) for the author(s) of this articlecan be found under https://doi.org/10.1002/adom.202300267© 2023 The Authors. Advanced Optical Materials published byWiley-VCH GmbH. This is an open access article under the terms of theCreative Commons Attribution-NonCommercial License, which permitsuse, distribution and reproduction in any medium, provided the originalwork is properly cited and is not used for commercial purposes.DOI: 10.1002/adom.2023002671. IntroductionDuring the last decade, 3D organic–inorganic halide perovskites (OIHPs) haveemerged as promising absorber materialsfor photovoltaic applications due to theirsuperior properties such as high absorp-tion coefficient, long diffusion length ofthe charge carriers, fast charge transport,and tunable bandgap. The 3D OIHPs havedemonstrated rapid increase in powerconversion efficiency (PCE) from 3.8% to25.2%.[1–9]On the other hand, their mod-erate intrinsic stability against moistureand heat still has been a concern with aview on possible commercialization.[10–14]Instability of the 3D methyl ammoniumlead iodide (MAPI) perovskite is assumedto be due to its crystalline structure. Ionicmigration is now well recognized to affectthe photovoltaic properties of perovskitesolar cells. Especially, the ionic migrationcauses the generation and displacement ofvacancies in perovskite materials. OIHPsare mixed ionic–electronic conductors withiodide ions as the majority of ionic carriers.D. KovachevaInstitute of General and Inorganic ChemistryBulgarian Academy of SciencesSofia 1113, BulgariaM. A. Reus, P. Müller-BuschbaumTUM School of Natural SciencesDepartment of PhysicsChair for Functional MaterialsTechnical University of MunichJames-Franck-Str. 1, 85748 Garching, GermanyN. F. HartmannAttocube systems AGNanoscale AnalyticsneaspecEglfinger Weg 2, 85540 Haar, GermanyS. Lotfi, J. P. HofmannSurface Science LaboratoryDepartment of Materials and Earth SciencesTechnical University of DarmstadtOtto-Berndt-Str. 3, 64287 Darmstadt, GermanyAdv. Optical Mater.2023,11, 23002672300267 (1 of 13)© 2023 The Authors. Advanced Optical Materials published by Wiley-VCH GmbH
Keywords: perovskites, solar cells, passivation
Published in RUNG: 04.12.2023; Views: 382; Downloads: 2
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2.
Measurement of the cosmic ray spectrum with the Pierre Auger Observatory
Daniela Mockler, Andrej Filipčič, Gašper Kukec Mezek, Ahmed Saleh, Samo Stanič, Marta Trini, Serguei Vorobiov, Lili Yang, Danilo Zavrtanik, Marko Zavrtanik, Lukas Zehrer, 2019, published scientific conference contribution

Abstract: The flux of ultra-high energy cosmic rays above 3×10[sup]17 eV has been measured with unprecedented precision at the Pierre Auger Observatory. The flux of the cosmic rays is determined by four different measurements. The surface detector array provides three data sets, two formed by dividing the data into two zenith angle ranges, and one obtained from a nested, denser detector array. The fourth measurement is obtained with the fluorescence detector. By combining all four data sets, the all-sky flux of cosmic rays is determined. The spectral features are discussed in detail and systematic uncertainties are addressed.
Keywords: ultra-high-energy cosmic rays (UHECRs), Pierre Auger Observatory, UHECR energy spectrum
Published in RUNG: 11.10.2023; Views: 615; Downloads: 6
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3.
Sustainable impacts for studying and innovating through art, science and technology : MAST sustainability plan
Kornélia Kiss, Peter Purg, Simon Gmajner, Nayarí Castillo-Rutz, Daniela Urem, Sergi Bermúdez, 2020, treatise, preliminary study, study

Abstract: The MAST Sustainability Plan reflects the actions and strategies of the MAST project consortium that are to safeguard the longevity of the project’s positive impacts both on the level of participating institutions, the manifold stakeholder groups involved, and the broader network of (future) partnerships that may evolve and benefit from the project’s results.
Keywords: Sustainability, exploitation, project, Arts Science and Technology
Published in RUNG: 10.02.2021; Views: 2215; Downloads: 62
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4.
MAST PROFESSIONAL and PERSONAL DEVELOPMENT : Career Development Guide for Art – Science – Technology
Daniela Urem, Peter Purg, Tere Badia, Jernej Gerbec Čuček, Nayari Castillo Rutz, Sergi Bermudez di Badia, Simon Gmajner, professional monograph

Abstract: The MAST project Career Development Guide serves as a professional and personal development reference in the realm of Art, Science and Technology (AST). It aims to support a variety of needs for emerging practitioners and will also continue to be supported through Unicult learning events and opportunities through the project network partnerships.
Keywords: career, future of work, professional development, personal development, capacity building
Published in RUNG: 10.02.2021; Views: 2095; Downloads: 0
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5.
ŽANRSKOST LITERARNEGA OPUSA JANJE VIDMAR : DIPLOMSKO DELO
Daniela Paj, 2020, undergraduate thesis

Abstract: V diplomskem delu se osredotočam na analizo naslednjih literarnih del Janje Vidmar: Punce za znoret, Hiša groze, Kdo je ubil Emilijo K.?, Bučko Superga, Princeska z napako, Angie, Brez, Pink, Ameriški prijatelj, Blues za Saro, Fantje iz gline, Debeluška, Vrtiljak čudežev, Uspavanka za mladega očka, Potovanje groze in Tretja možnost. Na začetku na podlagi teorij Mirana Hladnika, Marka Juvana, Alojzije Zupan Sosič, Barbare Pregelj in Jožice Jožef Beg, predstavim pojme kanonizirana in trivialna literatura ter žanrski sinkretizem, se posvetim pojmu realizem v sodobni slovenski mladinski književnosti in nakažem smer žanrskosti v delih Janje Vidmar. Sledi predstavitev avtorice in njenega literarnega ustvarjanja ter opis pripovednih elementov (protagonist, čas/prostor, pripovedovalec, fokalizacija). V osrednjem delu analiziram besedila Janje Vidmar v povezavi z žanrskostjo in na podlagi te analize ugotovim, da gre pri njih za prepletanje različnih žanrov (žanrski sinkretizem).
Keywords: Mladinska književnost, realizem, pripovedna perspektiva, proza, žanri, perspektiva, žanrski sinkretizem, Janja Vidmar.
Published in RUNG: 13.01.2021; Views: 3454; Downloads: 101
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The Multifaceted Complexity of Genetic Diseases: A Lesson from Pseudoxanthoma Elasticum
Daniela Quaglino, Federica Boraldi, Giulia Annovi, Ivonne Pasquali Ronchetti, 2011, independent scientific component part or a chapter in a monograph

Keywords: Genetic pathology, skin, morphology, PXE
Published in RUNG: 23.08.2019; Views: 3329; Downloads: 0
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8.
Fibroblast involvement in soft connective tissue calcification
Ivonne Pasquali Ronchetti, Federica Boraldi, Giulia Annovi, Paolo Cianciulli, Daniela Quaglino, 2013, review article

Abstract: Soft connective tissue calcification is not a passive process, but the consequence of metabolic changes of local mesenchymal cells that, depending on both genetic and environmental factors, alter the balance between pro- and anti-calcifying pathways. While the role of smooth muscle cells and pericytes in ectopic calcifications has been widely investigated, the involvement of fibroblasts is still elusive. Fibroblasts isolated from the dermis of pseudoxanthoma elasticum (PXE) patients and of patients exhibiting PXE-like clinical and histopathological findings offer an attractive model to investigate the mechanisms leading to the precipitation of mineral deposits within elastic fibers and to explore the influence of the genetic background and of the extracellular environment on fibroblast-associated calcifications, thus improving the knowledge on the role of mesenchymal cells on pathologic mineralization.
Keywords: fibroblasts, PXE, PXE-likedisorders, elastin, extracellularmatrix, ectopiccalcification, mesenchymal stromalcells
Published in RUNG: 23.08.2019; Views: 3060; Downloads: 0
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