1. A European aerosol phenomenology - 7 : high-time resolution chemical characteristics of submicron particulate matter across EuropeM. Bressi, F. Cavalli, Jean-Philippe Putaud, R. Fröhlich, J. -E. Petit, W. Aas, M. Äijälä, A. Alastuey, J. D. Allan, M. Aurela, Iasonas Stavroulas, Marta Via, 2021, izvirni znanstveni članek Opis: Similarities and differences in the submicron atmospheric aerosol chemical composition are analyzed from a unique set of measurements performed at 21 sites across Europe for at least one year. These sites are located between 35 and 62°N and 10° W – 26°E, and represent various types of settings (remote, coastal, rural, industrial, urban). Measurements were all carried out on-line with a 30-min time resolution using mass spectroscopy based instruments known as Aerosol Chemical Speciation Monitors (ACSM) and Aerosol Mass Spectrometers (AMS) and following common measurement guidelines. Data regarding organics, sulfate, nitrate and ammonium concentrations, as well as the sum of them called non-refractory submicron aerosol mass concentration ([NR-PM1]) are discussed. NR-PM1 concentrations generally increase from remote to urban sites. They are mostly larger in the mid-latitude band than in southern and northern Europe. On average, organics account for the major part (36–64%) of NR-PM1 followed by sulfate (12–44%) and nitrate (6–35%). The annual mean chemical composition of NR-PM1 at rural (or regional background) sites and urban background sites are very similar. Considering rural and regional background sites only, nitrate contribution is higher and sulfate contribution is lower in mid-latitude Europe compared to northern and southern Europe. Large seasonal variations in concentrations (μg/m³) of one or more components of NR-PM1 can be observed at all sites, as well as in the chemical composition of NR-PM1 (%) at most sites. Significant diel cycles in the contribution to [NR-PM1] of organics, sulfate, and nitrate can be observed at a majority of sites both in winter and summer. Early morning minima in organics in concomitance with maxima in nitrate are common features at regional and urban background sites. Daily variations are much smaller at a number of coastal and rural sites. Looking at NR-PM1 chemical composition as a function of NR-PM1 mass concentration reveals that although organics account for the major fraction of NR-PM1 at all concentration levels at most sites, nitrate contribution generally increases with NR-PM1 mass concentration and predominates when NR-PM1 mass concentrations exceed 40 μg/m³ at half of the sites.
Ključne besede: aerosol, chemical composition, mass spectrometry, phenomenology
Objavljeno v RUNG: 10.05.2024; Ogledov: 132; Prenosov: 2
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2. Ambient carbonaceous aerosol levels in Cyprus and the role of pollution transport from the Middle EastAliki Christodoulou, Iasonas Stavroulas, Mihalis Vrekoussis, Maximillien Desservettaz, Michael Pikridas, Elie Bimenyimana, Jonilda Kushta, Matic Ivančič, Martin Rigler, Philippe Goloub, 2023, izvirni znanstveni članek Opis: Abstract. The geographical origin and source apportionment of submicron carbonaceous aerosols (organic aerosols, OAs, and black carbon, BC) have been investigated here for the first time, deploying high time-resolution measurements at an urban background site of Nicosia, the capital
city of Cyprus, in the eastern Mediterranean. This study covers a half-year
period, encompassing both the cold and warm periods with continuous
observations of the physical and chemical properties of PM1 performed
with an Aerosol Chemical Speciation Monitor (ACSM), an aethalometer,
accompanied by a suite of various ancillary offline and online measurements. Carbonaceous aerosols were dominant during both seasons (cold and warm periods), with a contribution of 57 % and 48 % to PM1, respectively, and exhibited recurrent intense nighttime peaks (> 20–30 µg m−3) during the cold period, associated with local domestic heating. The findings of this study show that high concentrations of sulfate (close to 3 µg m−3) were continuously recorded, standing among the highest ever reported for Europe and originating from the Middle East region. Source apportionment of the OA and BC fractions was performed using the
positive matrix factorization (PMF) approach and the combination of two
models (aethalometer model and multilinear regression), respectively. Our
study revealed elevated hydrocarbon-like organic aerosol (HOA)
concentrations in Nicosia (among the highest reported for a European urban
background site), originating from a mixture of local and regional
fossil fuel combustion sources. Although air masses from the Middle East had
a low occurrence and were observed mostly during the cold period, they were
shown to strongly affect the mean concentrations levels of BC and OA in
Nicosia during both seasons. Overall, the present study brings to our
attention the need to further characterize primary and secondary
carbonaceous aerosols in the Middle East, an undersampled region
characterized by continuously increasing fossil fuel (oil and gas) emissions
and extreme environmental conditions, which can contribute to photochemical
ageing.
Ključne besede: PM1, BC, source apportionment, Cyprus, long range transport
Objavljeno v RUNG: 10.05.2024; Ogledov: 134; Prenosov: 2
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3. Recommendations for reporting equivalent black carbon (eBC) mass concentrations based on long-term pan-European in-situ observationsMarjan Savadkoohi, Marco Pandolfi, Olivier Favez, Jean-Philippe Putaud, Konstantinos Eleftheriadis, Markus Fiebig, Philip Hopke, Paolo Laj, A. Wiedensohler, Griša Močnik, 2024, izvirni znanstveni članek Opis: A reliable determination of equivalent black carbon (eBC) mass concentrations derived from filter absorption photometers (FAPs) measurements depends on the appropriate quantification of the mass absorption cross-section (MAC) for converting the absorption coefficient (babs) to eBC. This study investigates the spatial–temporal variability of the MAC obtained from simultaneous elemental carbon (EC) and babs measurements performed at 22 sites. We compared different methodologies for retrieving eBC integrating different options for calculating MAC including: locally derived, median value calculated from 22 sites, and site-specific rolling regression MAC. The eBC concentrations that underwent correction using these methods were identified as LeBC (local MAC), MeBC (median MAC), and ReBC (Rolling MAC) respectively. Pronounced differences (up to more than 50 %) were observed between eBC as directly provided by FAPs (NeBC; Nominal instrumental MAC) and ReBC due to the differences observed between the experimental and nominal MAC values. The median MAC was 7.8 ± 3.4 m2/g from 12 aethalometers at 880 nm, and 10.6 ± 4.7 m2/g from 10 MAAPs at 637 nm. The experimental MAC showed significant site and seasonal dependencies, with heterogeneous patterns between summer and winter in different regions. In addition, long-term trend analysis revealed statistically significant (s.s.) decreasing trends in EC. Interestingly, we showed that the corresponding corrected eBC trends are not independent of the way eBC is calculated due to the variability of MAC. NeBC and EC decreasing trends were consistent at sites with no significant trend in experimental MAC. Conversely, where MAC showed s.s. trend, the NeBC and EC trends were not consistent while ReBC concentration followed the same pattern as EC. These results underscore the importance of accounting for MAC variations when deriving eBC measurements from FAPs and emphasizes the necessity of incorporating EC observations to constrain the uncertainty associated with eBC.
Ključne besede: equivalent black carbon, mass absorption cross-section, filter absorption photometers, elemental carbon, absorption, site specific MAC, rolling MAC
Objavljeno v RUNG: 04.03.2024; Ogledov: 432; Prenosov: 3
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4. Aeolus calibration, validation and science campaignsThorsten Fehr, Vassilis Amiridis, Sebastian Bley, Philippe Cocquerez, Christian Lemmerz, Griša Močnik, Gail Skofronick-Jackson, Anne Grete Straume, 2020, objavljeni povzetek znanstvenega prispevka na konferenci Opis: Since 2007, a series of ESA supported airborne campaigns have been essential to the development of the Aeolus Doppler Wind Lidar satellite mission, which was successfully launched on 22 September 2018 and is providing a novel wind and aerosol profile data.
A core element of the Aeolus Cal/Val activities is DLR’s A2D wind lidar on-board the DLR Falcon aircraft, an airborne demonstrator for the Aeolus ALADIN satellite instrument flown in combination with the 2-µm Doppler Wind Lidar reference system. Following the pre-launch WindVal-I and –II campaigns in 2015 and 2016, a number of calibration and validation campaigns have been successfully implemented: WindVal-III providing early Cal/Val results in November 2018 only three months after the Aeolus launch, AVATAR-E in May 2019 focussing on the Cal/Val over Central Europe, and AVATAR-I in September 2019 providing Cal/Val information in the North Atlantic and Arctic flying from Iceland.
The airborne validation is also being supported through balloon flights in the tropical UTLS and lower stratosphere in the frame of the CNES Stratéole-2 stratospheric balloon activities. In the frame of the ESA supported pre-Stratéole-2 campaign, eight stratospheric balloons have been launched from the Seychelles in November/December 2019 providing unique upper level wind data for the Aeolus validation.
The largest impact of the Aeolus observations is expected in the Tropics, and in particular over the Tropical oceans, where only a limited number of wind profile information is provided by ground based observations. Aeolus provides key direct measurements which are of importance to correctly constrain the wind fields in models. In addition, Aeolus observations have the potential to further enhance our current knowledge on aerosols and clouds by globally providing optical properties products that include atmospheric backscatter and extinction coefficient profiles, lidar ratio profiles and scene classification. In the tropics, a particularly interesting case is the outflow of Saharan dust and its impact on micro-physics in tropical cloud systems. The region off the coast of West Africa allows the study of the Saharan Aerosol layer, African Easterly Waves and Jets, Tropical Easterly Jet, as well as the deep convection in ITCZ.
Together with international partners, ESA is currently implementing a Tropical campaign in July 2020 with its base in Cape Verde that comprises both airborne and ground-based activities addressing the tropical winds and aerosol validation, as well as science objectives. The airborne component includes the DLR Falcon-20 carrying the A2D and 2-µm Doppler Wind lidars, the NASA P-3 Orion with the DAWN and HALO lidar systems, the APR Ku-, Ka- and W-band Doppler radar and drop sondes, and a Slovenian small aircraft providing in-situ information from aethalometers, nephelometers and optical particle counters. The ground-based component led by the National Observatory of Athens is a collaboration of European teams providing aerosol and cloud measurements with a range of lidar, radar and radiometer systems, as well as a drone providing in-situ aerosol observations. In addition, the participation airborne capabilities by NOAA and LATMOS/Meteo France are currently being investigated.
This paper will provide a summary of the Aeolus campaign focussing on the planned tropical campaign.
Ključne besede: Aeolus satellite, ALADIN, aerosol, validation
Objavljeno v RUNG: 23.08.2022; Ogledov: 1423; Prenosov: 57
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5. The impact of observing strategy on cosmological constraints with LSSTMichelle Lochner, Dan Scolnic, Husni Almoubayyed, Timo Anguita, Humna Awan, Eric Gawiser, Satya Gontcho A Gontcho, Melissa Lynn Graham, Philippe Gris, Tanja Petrushevska, 2022, izvirni znanstveni članek Ključne besede: cosmology, observing strategy, LSST, Vera Rubin Observatory
Objavljeno v RUNG: 07.04.2022; Ogledov: 1584; Prenosov: 62
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7. Overview of radiation induced point defects in silica-based optical fibersSylvain Girard, Antonino Alessi, Vincenzo De Michele, Youcef Ouerdane, A. Boukenter, Adriana Morana, Nicolas Richard, Philippe Paillet, Marco Cannas, Simonpietro Agnello, Imène Reghioua, Blaz Winkler, Layla Martin-Samos, Luigi Giacomazzi, Diego Di Francesca, Thierry Robin, 2019, pregledni znanstveni članek Ključne besede: optical fibers, point defects, radiation-induced attenuation, GLPC, NBOHC, STH, ODC, P-doping, Ge-doping, Al-doping
Objavljeno v RUNG: 09.05.2019; Ogledov: 3423; Prenosov: 0
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8. Radiation Effects on Optical Fibers and Fiber-Based SensorsSylvain Girard, A. Boukenter, Youcef Ouerdane, Nicolas Richard, Philippe Paillet, Layla Martin-Samos, Luigi Giacomazzi, Claude Marcandella, 2015, samostojni znanstveni sestavek ali poglavje v monografski publikaciji Ključne besede: Optical Fibers, radiation-induced point defects, dosimetry, ab-initio
Objavljeno v RUNG: 24.10.2018; Ogledov: 3785; Prenosov: 0
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