191. Electrolysis energy efficiency of highly concentrated FeCl[sub]2 solutions for power-to-solid energy storage technologyUroš Luin, Matjaž Valant, 2022, izvirni znanstveni članek Opis: An electrochemical cycle for the grid energy storage in the redox potential of Fe involves the electrolysis of a highly concentrated aqueous FeCl2 solution yielding solid iron deposits. For the high overall energy efficiency of the cycle, it is crucial to maximize the energy efficiency of the electrolysis process. Here we present a study of the influence of electrolysis parameters on the energy efficiency of such electrolysis, performed in an industrial-type electrolyzer. We studied the conductivity of the FeCl2 solution as a function of concentration and temperature and correlated it with the electrolysis energy efficiency. The deviation from the correlation indicated an important contribution from the conductivity of the ion-exchange membrane. Another important studied parameter was the applied current density. We quantitatively showed how the contribution of the resistance polarization increases with the current density, causing a decrease in overall energy efficiency. The highest energy efficiency of 89 ± 3% was achieved using 2.5 mol L−1 FeCl2 solution at 70 °C and a current density of 0.1 kA m−2. In terms of the energy input per Fe mass, this means 1.88 Wh g−1. The limiting energy input per mass of the Fe deposit was found to be 1.76 Wh g−1.
Ključne besede: electrolysis, ferrous chloride, iron deposition, energy efficiency
Objavljeno v RUNG: 16.02.2022; Ogledov: 1760; Prenosov: 75 (1 glas)
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192. Interface engineering of Ta[sub]3N[sub]5 thin film photoanode for highly efficient photoelectrochemical water splittingJie Fu, Zeyu Fan, Mamiko Nakabayashi, Huanxin Ju, Nadiia Pastukhova, Yequan Xiao, Chao Feng, Naoya Shibata, Kazunari Domen, Yanbo Li, 2022, izvirni znanstveni članek Opis: Interface engineering is a proven strategy to improve the efficiency of thin film semiconductor based solar energy conversion devices. Ta3N5 thin film photoanode is a promising candidate for photoelectrochemical (PEC) water splitting. Yet, a concerted effort to engineer both the bottom and top interfaces of Ta3N5 thin film photoanode is still lacking. Here, we employ n-type In:GaN and p-type Mg:GaN to modify the bottom and top interfaces of Ta3N5 thin film photoanode, respectively. The obtained In:GaN/Ta3N5/Mg:GaN heterojunction photoanode shows enhanced bulk carrier separation capability and better injection efficiency at photo- anode/electrolyte interface, which lead to a record-high applied bias photon-to-current efficiency of 3.46% for Ta3N5-based photoanode. Furthermore, the roles of the In:GaN and Mg:GaN layers are distinguished through mechanistic studies. While the In:GaN layer con- tributes mainly to the enhanced bulk charge separation efficiency, the Mg:GaN layer improves the surface charge inject efficiency. This work demonstrates the crucial role of proper interface engineering for thin film-based photoanode in achieving efficient PEC water splitting.
Ključne besede: photocatalysis, renewable energy
Objavljeno v RUNG: 09.02.2022; Ogledov: 1771; Prenosov: 74
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193. Experimental and Theoretical Photoemission Study of Indole and Its Derivatives in the Gas PhaseO. Plekan, H. Sa'adeh, A. Ciavardini, C. Callegari, G. Cautero, C. Dri, M. Di Fraia, K.C. Prince, R. Richter, R. Sergo, L. Stebel, M. Devetta, D. Faccialà, C. Vozzi, L. Avaldi, P. Bolognesi, M.C Castrovilli, D. Catone, M. Coreno, F. Zuccaro, E. Bernes, G. Fronzoni, D. Toffoli, 2020, izvirni znanstveni članek Ključne besede: Binding energy, Calculations, Core levels, Electronic structure, Ionization of gases, Ionization potential, Molecular orbitals, Photoelectron spectroscopy, Photoelectrons, Photoemission, Photoionization, Photons, Polycyclic aromatic hydrocarbons, X rays
Objavljeno v RUNG: 21.01.2022; Ogledov: 1873; Prenosov: 0
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194. Testing effects of Lorentz invariance violation in the propagation of astroparticles with the Pierre Auger ObservatoryP. Abreu, Andrej Filipčič, Jon Paul Lundquist, Samo Stanič, Serguei Vorobiov, Danilo Zavrtanik, Marko Zavrtanik, Lukas Zehrer, 2022, izvirni znanstveni članek Ključne besede: cosmic ray experiments, ultra high energy, cosmic rays, physics of the early universe, Pierre Auger Observatory, Lorentz invariance violation effects
Objavljeno v RUNG: 18.01.2022; Ogledov: 1651; Prenosov: 38
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198. Application of machine learning techniques for cosmic ray event classification and implementation of a real-time ultra-high energy photon search with the surface detector of the Pierre Auger Observatory : dissertationLukas Zehrer, 2021, doktorska disertacija Opis: Despite their discovery already more than a century ago, Cosmic Rays (CRs) still did not divulge all their properties yet. Theories about the origin of ultra-high energy (UHE, > 10^18 eV) CRs predict accompanying primary photons. The existence of UHE photons can be investigated with the world’s largest ground-based experiment for detection of CR-induced extensive air showers (EAS), the Pierre Auger Observatory, which offers an unprecedented exposure to rare UHE cosmic particles.
The discovery of photons in the UHE regime would open a new observational window to the Universe, improve our understanding of the origin of CRs, and potentially uncloak new physics beyond the standard model.
The novelty of the presented work is the development of a "real-time" photon candidate event stream to a global network of observatories, the Astrophysical Multimessenger Observatory Network (AMON). The stream classifies CR events observed by the Auger surface detector (SD) array as regards their probability to be photon nominees, by feeding to advanced machine learning (ML) methods observational air shower parameters of individual CR events combined in a multivariate analysis (MVA).
The described straightforward classification procedure further increases the Pierre Auger Observatory’s endeavour to contribute to the global effort of multi-messenger (MM) studies of the highest energy astrophysical phenomena, by supplying AMON partner observatories the possibility to follow-up detected UHE events, live or in their archival data.
Ključne besede: astroparticle physics, ultra-high energy cosmic rays, ultra-high energy photons, extensive air showers, Pierre Auger Observatory, multi-messenger, AMON, machine learning, multivariate analysis, dissertations
Objavljeno v RUNG: 27.10.2021; Ogledov: 2848; Prenosov: 150
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199. Experimental bounds on sterile-active neutrino mixing anglesMihael Petač, 2015, magistrsko delo Opis: Despite the success of the Standard Model in the last few decades, we know it is not complete. There is strong motivation for assuming the existence of additional heavy neutral leptons, which can account for active neutrino masses and possibly also have cosmological implications. In this work I consider the Standard Model with two neutral lepton singlets (sterile neutrinos) with degenerated masses in the range 20MeV - 2GeV. The constraints on the active-sterile neutrino mixing angles are evaluated based on recent neutrino oscillations data. Using these constraints the bounds from accelerator experiments are reanalyzed for the case of the considered model. Finally, the results are compared with cosmological constraints coming from Big Bang nucleosynthesis and the nMSM resonant leptogenesis.
Ključne besede: Sterile neutrinos, Neutrino mixing, See-saw, High-Energy Physics - Phenomenology, High-Energy Physics - Experiments
Objavljeno v RUNG: 01.10.2021; Ogledov: 1765; Prenosov: 46
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200. Testing the predictions of axisymmetric distribution functions of galactic dark matter with hydrodynamical simulationsMihael Petač, Julien Lavalle, Arturo Núñez-Castiñeyra, Emmanuel Nezri, 2021, izvirni znanstveni članek Opis: Signal predictions for galactic dark matter (DM) searches often rely on assumptions regarding the DM phase-space distribution function (DF) in halos. This applies to both particle (e.g. p-wave suppressed or Sommerfeld-enhanced annihilation, scattering off atoms, etc.) and macroscopic DM candidates (e.g. microlensing of primordial black holes). As experiments and observations improve in precision, better assessing theoretical uncertainties becomes pressing in the prospect of deriving reliable constraints on DM candidates or trustworthy hints for detection. Most reliable predictions of DFs in halos are based on solving the steady-state collisionless Boltzmann equation (e.g. Eddington-like inversions, action-angle methods, etc.) consistently with observational constraints. One can do so starting from maximal symmetries and a minimal set of degrees of freedom, and then increasing complexity. Key issues are then whether adding complexity, which is computationally costy, improves predictions, and if so where to stop. Clues can be obtained by making predictions for zoomed-in hydrodynamical cosmological simulations in which one can access the true (coarse-grained) phase-space information. Here, we test an axisymmetric extension of the Eddington inversion to predict the full DM DF from its density profile and the total gravitational potential of the system. This permits to go beyond spherical symmetry, and is a priori well suited for spiral galaxies. We show that axisymmetry does not necessarily improve over spherical symmetry because the (observationally unconstrained) angular momentum of the DM halo is not generically aligned with the baryonic one. Theoretical errors are similar to those of the Eddington inversion though, at the 10-20% level for velocity-dependent predictions related to particle DM searches in spiral galaxies. We extensively describe the approach and comment on the results.
Ključne besede: galaxy dynamics, dark matter experiments, dark matter simulations, dark matter theory, cosmology, nongalactic astrophysics, astrophysics of galaxies, high energy physics
Objavljeno v RUNG: 01.10.2021; Ogledov: 2003; Prenosov: 65
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