| Title: | SYNTHESIS OF NOVEL GROUP 3 AND LANTHANIDES COMPLEXES CONTAINING THE FERROCENYL MOIETY |
|---|
| Authors: | ID Bortoluzzi, Marco (Mentor) More about this mentor... 
ID Lavrencic Stangar, Urska (Mentor) More about this mentor...
ID Segato, Jacopo (Author) |
|---|
| Files: |  Jacopo_Segato.pdf (4,17 MB)
MD5: 3E2A420C0CA71A0A185A5022A90811C9
|
|---|
| Language: | English |
|---|
| Work type: | Master's thesis/paper |
|---|
| Typology: | 2.09 - Master's Thesis |
|---|
| Organization: | FZO - Faculty of Environmental Sciences
|
|---|
| Abstract: | The thesis describes the synthesis of novel yttrium(III), europium(III) and ytterbium(III) complexes with polydentate ligands containing the ferrocenyl moiety. In particular, a chelating beta-diketonate ligand having formula [FcCOCHCOCH3]- has been used for the preparation of homo- and heteroleptic complexes, these last having N-donor ligands such as 1,10-phenanthroline or tris(3,5-dimethylpyrazol-1-yl)borate in their coordination sphere. Further complexes were obtained by reacting bis(diphenylphosphino)ferrocene dioxide with proper Group 3 and lanthanide precursors, having nitromalonaldehyde or bromomalonaldehyde as supporting ligands. In all the cases, the characterizations were corroborated by electrochemical measurements and diffusion spectroscopy. Reversible or quasi-reversible one-electron oxidation of the ferrocenyl moiety was detected for the new complexes, even if the corresponding ferricinium-based compounds resulted quite strong oxidants. |
|---|
| Keywords: | lanthanides, ferrocene, heteropolymetallic complexes, beta-diketonate, cyclovoltammetry |
|---|
| Place of publishing: | Nova Gorica |
|---|
| Year of publishing: | 2016 |
|---|
| PID: | 20.500.12556/RUNG-2832-aeb3f4c1-bcc6-905a-52d1-306781ec28f4 |
|---|
| COBISS.SI-ID: | 4611067 |
|---|
| NUK URN: | URN:SI:UNG:REP:LWRYRNHT |
|---|
| Publication date in RUNG: | 16.12.2016 |
|---|
| Views: | 7513 |
|---|
| Downloads: | 351 |
|---|
| Metadata: |    |
|---|
|
:
|
Copy citation |
|---|
| | | | Average score: | (0 votes) |
|---|
| Your score: | Voting is allowed only for logged in users. |
|---|
| Share: |  |
|---|
Hover the mouse pointer over a document title to show the abstract or click
on the title to get all document metadata. |
