| Naslov: | SYNTHESIS OF NOVEL GROUP 3 AND LANTHANIDES COMPLEXES CONTAINING THE FERROCENYL MOIETY |
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| Avtorji: | ID Bortoluzzi, Marco (Mentor) Več o mentorju... 
ID Lavrencic Stangar, Urska (Mentor) Več o mentorju...
ID Segato, Jacopo (Avtor) |
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| Datoteke: |  Jacopo_Segato.pdf (4,17 MB)
MD5: 3E2A420C0CA71A0A185A5022A90811C9
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| Jezik: | Angleški jezik |
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| Vrsta gradiva: | Magistrsko delo/naloga |
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| Tipologija: | 2.09 - Magistrsko delo |
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| Organizacija: | FZO - Fakulteta za znanosti o okolju
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| Opis: | The thesis describes the synthesis of novel yttrium(III), europium(III) and ytterbium(III) complexes with polydentate ligands containing the ferrocenyl moiety. In particular, a chelating beta-diketonate ligand having formula [FcCOCHCOCH3]- has been used for the preparation of homo- and heteroleptic complexes, these last having N-donor ligands such as 1,10-phenanthroline or tris(3,5-dimethylpyrazol-1-yl)borate in their coordination sphere. Further complexes were obtained by reacting bis(diphenylphosphino)ferrocene dioxide with proper Group 3 and lanthanide precursors, having nitromalonaldehyde or bromomalonaldehyde as supporting ligands. In all the cases, the characterizations were corroborated by electrochemical measurements and diffusion spectroscopy. Reversible or quasi-reversible one-electron oxidation of the ferrocenyl moiety was detected for the new complexes, even if the corresponding ferricinium-based compounds resulted quite strong oxidants. |
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| Ključne besede: | lanthanides, ferrocene, heteropolymetallic complexes, beta-diketonate, cyclovoltammetry |
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| Kraj izida: | Nova Gorica |
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| Leto izida: | 2016 |
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| PID: | 20.500.12556/RUNG-2832-aeb3f4c1-bcc6-905a-52d1-306781ec28f4 |
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| COBISS.SI-ID: | 4611067 |
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| NUK URN: | URN:SI:UNG:REP:LWRYRNHT |
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| Datum objave v RUNG: | 16.12.2016 |
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| Število ogledov: | 5867 |
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| Število prenosov: | 348 |
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| Metapodatki: |     |
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