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Naslov:Soot as a precursor for the low temperature synthesis of organometallic sodium carbide
Avtorji:ID Swapna, Mohanachandran Nair Sindhu, UNIVERSITY OF KERALA (Avtor)
ID H V, SARITHA DEVI, UNIVERSITY OF KERALA (Avtor)
ID S, Sankararaman, UNIVERSITY OF KERALA (Avtor)
Datoteke: Gradivo nima datotek, ki so prostodostopne za javnost. Gradivo je morda fizično dosegljivo v knjižnici fakultete, zalogo lahko preverite v COBISS-u. Povezava se odpre v novem oknu
Jezik:Angleški jezik
Vrsta gradiva:Delo ni kategorizirano
Tipologija:1.01 - Izvirni znanstveni članek
Organizacija:UNG - Univerza v Novi Gorici
Opis:The carbonaceous soot finds a wide range of applications in many fields due to the richness of various allotropes of carbon. The present work explores the possibility of least investigated sodium carbide (Na2C2) as a potential semiconducting material for photonic applications. The soot, formed by the incomplete combustion of gingelly oil is taken as the carbon precursor for the low-temperature synthesis of the industrially significant organometallic Na2C2. The morphological modifications are analyzed using High-Resolution Transmission Electron Microscope and elemental study is carried out by Energy Dispersive Spectroscopy and x-ray dot mapping. The formation of Na2C2 is primarily identified from x-ray powder diffraction pattern and further confirmed by other structural and thermal analysis techniques such as Fourier Transform Infrared, Raman spectroscopy, and Thermogravimetry. The region of optical absorption, bandgap, as well as its emission properties are studied by recording the Ultraviolet-Visible and Photoluminescence spectrum. The Tauc plot analysis suggests its semiconducting nature with direct bandgap energy of 2.08 eV. The analysis with the help of CIE, and power spectrum reveal a prominent blue emission around 440 nm irrespective of excitation in the UV region. Thus, the major highlights of this work lie in two factors- firstly, the effective utilization of the soot and secondly, easier low-temperature and cost-effective synthesis of semiconducting Na2C2 for photonic applications.
Ključne besede:carbonaceous soot, sodium carbide, photonic applications
Verzija publikacije:Objavljena publikacija
Leto izida:2019
Št. strani:9
Številčenje:10, 6
PID:20.500.12556/RUNG-7415 Novo okno
COBISS.SI-ID:113826563 Novo okno
DOI:10.1088/2053-1591/ab3ecf Novo okno
NUK URN:URN:SI:UNG:REP:CQP3ENEE
Datum objave v RUNG:05.07.2022
Število ogledov:1132
Število prenosov:0
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Gradivo je del revije

Naslov:Materials Research Express
Založnik:INSTITUTE OF PHYSICS
Leto izida:2019
ISSN:2053-1591

Licence

Licenca:CC BY-NC-ND 4.0, Creative Commons Priznanje avtorstva-Nekomercialno-Brez predelav 4.0 Mednarodna
Povezava:http://creativecommons.org/licenses/by-nc-nd/4.0/deed.sl
Opis:Najbolj omejujoča licenca Creative Commons. Uporabniki lahko prenesejo in delijo delo v nekomercialne namene in ga ne smejo uporabiti za nobene druge namene.
Začetek licenciranja:29.06.2022

Sekundarni jezik

Jezik:Ni določen
Opis:The carbonaceous soot finds a wide range of applications in many fields due to the richness of various allotropes of carbon. The present work explores the possibility of least investigated sodium carbide (Na2C2) as a potential semiconducting material for photonic applications. The soot, formed by the incomplete combustion of gingelly oil is taken as the carbon precursor for the low-temperature synthesis of the industrially significant organometallic Na2C2. The morphological modifications are analyzed using High-Resolution Transmission Electron Microscope and elemental study is carried out by Energy Dispersive Spectroscopy and x-ray dot mapping. The formation of Na2C2 is primarily identified from x-ray powder diffraction pattern and further confirmed by other structural and thermal analysis techniques such as Fourier Transform Infrared, Raman spectroscopy, and Thermogravimetry. The region of optical absorption, bandgap, as well as its emission properties are studied by recording the Ultraviolet-Visible and Photoluminescence spectrum. The Tauc plot analysis suggests its semiconducting nature with direct bandgap energy of 2.08 eV. The analysis with the help of CIE, and power spectrum reveal a prominent blue emission around 440 nm irrespective of excitation in the UV region. Thus, the major highlights of this work lie in two factors- firstly, the effective utilization of the soot and secondly, easier low-temperature and cost-effective synthesis of semiconducting Na2C2 for photonic applications
Ključne besede:sodium carbide, gingelly oil soot, carbon nanoparticle


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