| Naslov: | Crystallizing covalent organic frameworks from metal organic framework through chemical induced-phase engineering |
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| Avtorji: | ID Khayum Mohammed, Abdul (Avtor)
ID Gaber, Safa (Avtor)
ID Raya, Jesus (Avtor)
ID Škorjanc, Tina (Avtor)
ID Elmerhi, Nada (Avtor)
ID Stephen, Sasi (Avtor)
ID Pena-Sánchez, Pilar (Avtor)
ID Gándara, Felipe (Avtor)
ID Hinder, Steven (Avtor)
ID Baker, Mark A. (Avtor)
ID Polychronopoulou, Kyriaki (Avtor)
ID Shetty, Dinesh (Avtor) |
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| Datoteke: |  https://www.nature.com/articles/s41598-023-46573-3
 s41598-023-46573-3.pdf (3,64 MB)
MD5: 43250986A83C6994C1C51874FD645EA6
https://www.nature.com/articles/s41598-023-46573-3
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| Jezik: | Angleški jezik |
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| Vrsta gradiva: | Neznano |
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| Tipologija: | 1.01 - Izvirni znanstveni članek |
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| Organizacija: | UNG - Univerza v Novi Gorici
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| Opis: | The ordered porous frameworks like MOFs and COFs are generally constructed using the monomers through distinctive metal-coordinated and covalent linkages. Meanwhile, the inter-structural transition between each class of these porous materials is an under-explored research area. However, such altered frameworks are expected to have exciting features compared to their pristine versions. Herein, we have demonstrated a chemical-induction phase-engineering strategy to transform a two dimensional conjugated Cu-based SA-MOF (Cu-Tp) into 2D-COFs (Cu-TpCOFs). The structural phase transition offered in-situ pore size engineering from 1.1 nm to 1.5–2.0 nm. Moreover, the Cu-TpCOFs showed uniform and low percentage-doped (~ 1–1.5%) metal distribution and improved crystallinity, porosity, and stability compared to the parent Cu-Tp MOF. The construction of a framework from another framework with new linkages opens interesting opportunities for phase-engineering. |
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| Ključne besede: | metal organic framework, covalent organic framework, phase engineering, chemical transformation, porous materials |
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| Datum objave: | 01.01.2023 |
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| Leto izida: | 2023 |
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| Št. strani: | str. 1-7 |
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| Številčenje: | Vol. 13, article no. ǂ19443 |
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| PID: | 20.500.12556/RUNG-8621-0d201bce-5b61-5f43-f9ae-525909bf51b0  |
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| COBISS.SI-ID: | 171577091 |
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| UDK: | 54 |
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| ISSN pri članku: | 2045-2322 |
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| DOI: | 10.1038/s41598-023-46573-3 |
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| NUK URN: | URN:SI:UNG:REP:BA8JVMRY |
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| Datum objave v RUNG: | 10.11.2023 |
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| Število ogledov: | 718 |
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| Število prenosov: | 5 |
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| Metapodatki: |     |
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