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Title:Characterization of the particle size distribution, mineralogy, and Fe mode of occurrence of dust-emitting sediments from the Mojave Desert, California, USA
Authors:ID Gonzalez-Romero, Adolfo (Author)
ID González-Flórez, Cristina (Author)
ID Panta, Agnesh (Author)
ID Yus-Díez, Jesús (Author)
ID Córdoba, Patricia (Author)
ID Alastuey, Andrés (Author)
ID Jiménez-Moreno, Natalia (Author)
ID Hernández-Chiriboga, Melani (Author)
ID Kandler, Konrad (Author)
ID Klose, Martina (Author), et al.
Files:.pdf RAZ_Gonzalez-Romero_Adolfo_2024.pdf (10,28 MB)
MD5: 9C8B3ECFED69858CB8D48FE80408DDF3
 
URL https://acp.copernicus.org/articles/24/9155/2024/acp-24-9155-2024.pdf
 
Language:English
Work type:Unknown
Typology:1.01 - Original Scientific Article
Organization:UNG - University of Nova Gorica
Abstract:Abstract. Constraining dust models to understand and quantify the effect of dust upon climate and ecosystems requires comprehensive analyses of the physiochemical properties of dust-emitting sediments in arid regions. Building upon previous studies in the Moroccan Sahara and Iceland, we analyse a diverse set of crusts and aeolian ripples (n=55) from various potential dust-emitting basins within the Mojave Desert, California, USA. Our focus is on characterizing the particle size distribution (PSD), mineralogy, aggregation/cohesion state, and Fe mode of occurrence. Our results show differences in fully and minimally dispersed PSDs, with crusts exhibiting average median diameters of 92 and 37 µm, respectively, compared to aeolian ripples with 226 and 213 µm, respectively. Mineralogical analyses unveiled strong variations between crusts and ripples, with crusts being enriched in phyllosilicates (24 % vs. 7.8 %), carbonates (6.6 % vs. 1.1 %), Na salts (7.3 % vs. 1.1 %), and zeolites (1.2 % and 0.12 %) and ripples being enriched in feldspars (48 % vs. 37 %), quartz (32 % vs. 16 %), and gypsum (4.7 % vs. 3.1 %). The size fractions from crust sediments display a homogeneous mineralogy, whereas those of aeolian ripples display more heterogeneity, mostly due to different particle aggregation. Bulk Fe content analyses indicate higher concentrations in crusts (3.0 ± 1.3 wt %) compared to ripples (1.9 ± 1.1 wt %), with similar proportions in their Fe mode of occurrence: nano-sized Fe oxides and readily exchangeable Fe represent ∼1.6 %, hematite and goethite ∼15 %, magnetite/maghemite ∼2.0 %, and structural Fe in silicates ∼80 % of the total Fe. We identified segregation patterns in the PSD and mineralogy differences in Na salt content within the Mojave basins, which can be explained by sediment transportation dynamics and precipitates due to groundwater table fluctuations described in previous studies in the region. Mojave Desert crusts show similarities with previously sampled crusts in the Moroccan Sahara in terms of the PSD and readily exchangeable Fe yet exhibit substantial differences in mineralogical composition, which should significantly influence the characteristic of the emitted dust particles.
Keywords:mineral dust, iron oxides
Publication status:Published
Publication version:Version of Record
Publication date:01.01.2024
Year of publishing:2024
Number of pages:str. 9155-9176
Numbering:Vol. 24, issue 16
PID:20.500.12556/RUNG-9512-256aebb8-9053-ffc4-7e79-69dc9cee46af New window
COBISS.SI-ID:216982531 New window
UDC:502.3/.7
ISSN on article:1680-7324
eISSN:1680-7324
DOI:10.5194/acp-24-9155-2024 New window
NUK URN:URN:SI:UNG:REP:0LV8073T
Publication date in RUNG:29.11.2024
Views:138
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Record is a part of a journal

Title:Atmospheric chemistry and physics
Shortened title:Atmos. chem. phys.
Publisher:European Geophysical Society, Copernicus GmbH
ISSN:1680-7324
COBISS.SI-ID:1959012 New window

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.
Licensing start date:22.08.2024

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