Repozitorij Univerze v Novi Gorici

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Naslov:Increased sensitivity in proton transfer reaction mass spectrometry by incorporation of a radio frequency ion funnel
Avtorji:ID Barber, Shane, Department of Chemistry, University of Leicester, University Road, Leicester LE1 7RH, U.K (Avtor)
ID Blake, Robert S, Department of Chemistry, University of Leicester, University Road, Leicester LE1 7RH, U.K (Avtor)
ID White, Iain R., Department of Chemistry, University of Leicester, University Road, Leicester LE1 7RH, U.K (Avtor)
ID Monks, Paul S, Department of Chemistry, University of Leicester, University Road, Leicester LE1 7RH, U.K (Avtor)
ID Reich, Fraser, Kore Technology Limited, Cambridgeshire Business Park, Ely, Cambridgeshire CB7 4EA, United Kingdom (Avtor)
ID Mullock, Stephen, Kore Technology Limited, Cambridgeshire Business Park, Ely, Cambridgeshire CB7 4EA, United Kingdom (Avtor)
ID Ellis, Andrew M, Department of Chemistry, University of Leicester, University Road, Leicester LE1 7RH, U.K (Avtor)
Datoteke: Gradivo nima datotek, ki so prostodostopne za javnost. Gradivo je morda fizično dosegljivo v knjižnici fakultete, zalogo lahko preverite v COBISS-u. Povezava se odpre v novem oknu
Jezik:Angleški jezik
Vrsta gradiva:Delo ni kategorizirano
Tipologija:1.01 - Izvirni znanstveni članek
Organizacija:UNG - Univerza v Novi Gorici
Opis:A drift tube capable of simultaneously functioning as an ion funnel is demonstrated in proton transfer reaction mass spectrometry (PTR-MS) for the first time. The ion funnel enables a much higher proportion of ions to exit the drift tube and enter the mass spectrometer than would otherwise be the case. An increase in the detection sensitivity for volatile organic compounds of between 1 and 2 orders of magnitude is delivered, as demonstrated using several compounds. Other aspects of analytical performance explored in this study include the effective E/N (ratio of electric field to number density of the gas) and dynamic range over which the drift tube is operated. The dual-purpose drift tube/ion funnel can be coupled to various types of mass spectrometers to increase the detection sensitivity and may therefore offer considerable benefits in PTR-MS work.
Ključne besede:Analytical performance, Detection sensitivity, Drift tube, Dynamic range, Ion funnels, Proton-transfer reaction mass spectrometry, Volatile organic compounds
Leto izida:2012
Št. strani:5387-5391
Številčenje:12, 84
PID:20.500.12556/RUNG-4913 Novo okno
COBISS.SI-ID:5420283 Novo okno
DOI:10.1021/ac300894t Novo okno
NUK URN:URN:SI:UNG:REP:D1FD3WSB
Datum objave v RUNG:18.07.2019
Število ogledov:2811
Število prenosov:0
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Gradivo je del revije

Naslov:Analytical Chemistry
Skrajšan naslov:Anal. Chem.
Založnik:American Chemical Society
Leto izida:2012
ISSN:00032700

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