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1.
ORR stability of Mn–Co/polypyrrole nanocomposite electrocatalysts studied by quasi in-situ identical-location photoelectron microspectroscopy
Maya Kiskinova, Claudio Mele, Hikmet Sezen, Benedetto Bozzini, Mattia Fanetti, Andrea Goldoni, Luca Gregoratti, Belen Aleman, Matteo Amati, Patrizia Bocchetta, 2016, original scientific article

Abstract: The stability of pyrolyzed Mn–Co/polypyrrole (PPy) nanocomposites towards the Oxygen Reduction Reaction (ORR) in alkaline solution, was studied with a close-knit group of complementary microscopic and space-resolved spectroscopic approaches: Atomic Force Microscopy (AFM), Scanning and High-Resolution Transmission Electron Microscopy (SEM, HRTEM) and identical-location Scanning PhotoElectron Microscopy (SPEM). Tracking quasi-in situ the morphochemical evolution of the Mn–Co/PPy catalyst upon electrochemical aging under ORR conditions by this multi-technique approach, has allowed to clarify the key physico-chemical processes underlying the dramatic impact of Co additions to stability improvement.
Found in: ključnih besedah
Summary of found: ...The stability of pyrolyzed Mn–Co/polypyrrole (PPy) nanocomposites towards the Oxygen Reduction Reaction (ORR) in alkaline...
Keywords: Mixed manganese oxides, Polypyrrole, Oxygen reduction, Electrocatalysis, Nanocomposites, X-ray photoelectron microspectroscopy
Published: 25.07.2016; Views: 2341; Downloads: 0
.pdf Fulltext (1,36 MB)

2.
Novel two-step vapor-phase synthesis of UV – Vis light active Fe2O3/WO3 nanocomposites for phenol degradation
Urška Lavrenčič Štangar, Olena Pliekhova, Mariangela Brisotto, Elza Bontempi, Cinzia Sada, Chiara Maccato, Alberto Gasparotto, Giorgio Carraro, Davide Barreca, 2016, original scientific article

Abstract: Supported Fe2O3/WO3 nanocomposites were fabricated by an original vapor phase approach, involving the chemical vapor deposition (CVD) of Fe2O3 on Ti sheets and the subsequent radio frequency (RF)-sputtering of WO3. Particular attention was dedicated to the control of the W/Fe ratio, in order to tailor the composition of the resulting materials. The target systems were analyzed by the joint use of complementary techniques, that is, X-ray diffraction (XRD), field emission-scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), energy dispersive X-ray spectroscopy (EDXS), X-ray photoelectron spectroscopy (XPS), secondary ion mass spectrometry (SIMS), and optical absorption spectroscopy. The results showed the uniform decoration of α-Fe2O3 (hematite) globular particles by tiny WO3 aggregates, whose content could be controlled by modulations of the sole sputtering time. The photocatalytic degradation of phenol in the liquid phase was selected as a test reaction for a preliminary investigation of the system behavior in wastewater treatment applications. The system activity under both UVand Vis light illumination may open doors for further material optimization in view of real-world end-uses.
Found in: ključnih besedah
Keywords: Fe2O3, WO3, Nanocomposites, Chemical vapor deposition, Sputtering, Photocatalysis
Published: 03.08.2016; Views: 2262; Downloads: 0
.pdf Fulltext (1,91 MB)

3.
CuO Quantum Dots Decorated TiO2 Nanocomposite Photocatalyst for Stable Hydrogen Generation
Valluri Durga Kumari, Saim Emin, Nagappagari Lakshmana Reddy, Shankar Muthukonda Venkatakrishnan, 2017, original scientific article

Found in: ključnih besedah
Summary of found: ...photocatalysis, nanocomposites, TiO2...
Keywords: photocatalysis, nanocomposites, TiO2
Published: 31.01.2018; Views: 993; Downloads: 0
.pdf Fulltext (8,78 MB)

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