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24. Synthesis and Characterization of MWCNT-COOH/Fe3O4 and CNT-COOH/Fe3O4/NiO Nanocomposites: Assessment of Adsorption and Photocatalytic PerformanceAdina Stegarescu, Humberto Cabrera, Hanna Budasheva, Maria-Loredana Soran, Ildiko Lung, Francesca Limosani, Dorota Korte, Matteo Amati, Gheorghe Borodi, Ocsana Opris, Monica Dan, Stefano Bellucci, 2022, original scientific article Keywords: carbon nanotubes, magnetite, tartrazine, photodegradation, adsorption, water decontamination Published in RUNG: 02.09.2022; Views: 1331; Downloads: 25 Full text (5,78 MB) |
25. Two-year-long high-time-resolution apportionment of primary and secondary carbonaceous aerosols in the Los Angeles Basin using an advanced total carbon–black carbon (TC-BC([lambda])) methodMatic Ivančič, Asta Gregorič, Gašper Lavrič Palancsai, Bálint Alföldy, Irena Ježek, Sina Hasheminassab, Payam Pakbin, Faraz Ahangar, Mohammad Sowlat, Steven Boddeker, Martin Rigler, 2022, original scientific article Keywords: carbonaceous aerosols, black carbon, brown carbon, Carbonaceous Aerosol Speciation System Published in RUNG: 04.08.2022; Views: 1465; Downloads: 8 Link to full text This document has many files! More... |
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30. Optical emission diagnosis of carbon nanoparticle incorporated chlorophyll for sensing applicationsMohanachandran Nair Sindhu Swapna, RAJ VIMAL, SARITHA DEVI H V, Sankararaman S, 2019, original scientific article Abstract: Chlorophyll fluorescence (Chl F) is widely used in sensing applications to understand terrestrial vegetation
and environmental and climatic variations. The increasing rates of industrialization and carbon emission
from internal combustion engines (ICEs) pose a threat to sustainable development. This study analyses
the impact of carbon nanoparticles (CNPs) from ICEs on the optical absorption and fluorescence emission of leaf pigments. Leaf pigments without and with CNPs were subjected to UV-visible and photo-luminescence (PL) spectroscopy analyses. The field emission scanning electron microscopy and high-resolution transmission electron microscopy images of CNPs showed their morphology. The Jablonski diagram of the CNP-incorporated chlorophyll system helped in understanding the fluorescence emission,internal conversion, and the exchange of energy between them. The variations in (i) total chlorophyll, (ii)
optical absorbance by total chlorophyll, (iii) PL emission peak (at 675 nm and 718 nm) intensities for different excitation wavelengths, and (iv) normalized absorbance at the PL emission peaks with different CNP concentrations were analysed by dividing into three regions. In Region I (0–0.625 mg ml−1 ), the
radiative component dominated the nonradiative component as a result of energy transfer from CNPs to chlorophyll. In Region II (0.625–1.2 mg ml−1 ), the increase in CNP concentration initiated diffusion into chloroplasts, resulting in the increase in the nonradiative part of total energy and decrease in PL peak
intensity. In Region III (1.2–2.5 mg ml−1
), the energy absorbed by the CNPs dissipated more nonradiatively, leading to a slow rate of increase in the radiative part. The visual response of PL emission, color purity,
and the distribution of the emitted energy over the spectrum studied with the help of CIE plots, power spectrum, and confocal fluorescence microscopy revealed the fluorescence emission in the red region. This study suggests the possibility of employing Chl F in agricultural, environmental, and biological fields
for sensing applications. Keywords: carbon nanoparticle, optical emission, fluorescence Published in RUNG: 05.07.2022; Views: 1146; Downloads: 0 This document has many files! More... |