131. Changes in black carbon emissions over Europe due to COVID-19 lockdownsNikolaos Evangeliou, Stephen M. Platt, Sabine Eckhardt, Cathrine Lund Myhre, Paolo Laj, L. Alados-Arboledas, John Backman, Benjamin T. Brem, Markus Fiebig, Jesús Yus-Díez, 2021, original scientific article Abstract: Abstract. Following the emergence of the severe acute respiratory syndrome coronavirus
2 (SARS-CoV-2) responsible for COVID-19 in December 2019 in Wuhan (China)
and its spread to the rest of the world, the World Health Organization
declared a global pandemic in March 2020. Without effective treatment in the
initial pandemic phase, social distancing and mandatory quarantines were
introduced as the only available preventative measure. In contrast to the
detrimental societal impacts, air quality improved in all countries in which
strict lockdowns were applied, due to lower pollutant emissions. Here we
investigate the effects of the COVID-19 lockdowns in Europe on ambient black
carbon (BC), which affects climate and damages health, using in situ
observations from 17 European stations in a Bayesian inversion framework. BC
emissions declined by 23 kt in Europe (20 % in Italy, 40 % in Germany,
34 % in Spain, 22 % in France) during lockdowns compared to the same
period in the previous 5 years, which is partially attributed to COVID-19
measures. BC temporal variation in the countries enduring the most drastic
restrictions showed the most distinct lockdown impacts. Increased particle
light absorption in the beginning of the lockdown, confirmed by assimilated
satellite and remote sensing data, suggests residential combustion was the
dominant BC source. Accordingly, in central and Eastern Europe, which
experienced lower than average temperatures, BC was elevated compared to the
previous 5 years. Nevertheless, an average decrease of 11 % was seen
for the whole of Europe compared to the start of the lockdown period, with
the highest peaks in France (42 %), Germany (21 %), UK (13 %), Spain
(11 %) and Italy (8 %). Such a decrease was not seen in the previous
years, which also confirms the impact of COVID-19 on the European emissions
of BC. Keywords: black carbon, covid-19, emissions, Europe Published in RUNG: 13.05.2024; Views: 627; Downloads: 4
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132. Summertime particulate matter and its composition in GreeceM. A. Tsiflikiotou, E. Kostenidou, D. K. Papanastasiou, D. Patoulias, Pavlos Zarmpas, D. Paraskevopoulou, E. Diapouli, Christos Kaltsonoudis, Kalliopi Florou, Iasonas Stavroulas, 2019, original scientific article Abstract: During the summer of 2012 a coordinated field campaign was conducted in multiple locations in Greece in order to characterize the ambient particulate matter (PM) levels, its chemical composition and the contribution of the regional and local sources. PM1, PM2.5 and PM10 samples were collected simultaneously at seven different sites in Greece: an urban and a suburban station in Patras, a suburban station in Thessaloniki, a suburban and an urban background station in Athens, a rural background station at the Navarino Environmental Observatory (NEO) in southwestern Peloponnese and a remote background site at Finokalia in the northeastern part of Crete. The sites were selected to facilitate the estimation of the contribution of the local emission sources and long range transport.
Sulfate and organics were the major PM1 components in all sites suggesting that high sulfate levels still remain in parts of Europe. The photochemistry of the Eastern Mediterranean can convert rapidly the emitted sulphur dioxide to sulfate. Our analysis indicated significant sulfate production over the area, with high sulfate levels, especially in the remote site of Finokalia, associated with air masses that had passed over Turkey. There was high regional secondary organic aerosol production dominating organic aerosol levels even in a major city like Athens. High organic aerosol levels were associated with air masses that had crossed the Balkans with a significant biogenic component. The average PM2.5 concentration ranged from 13 to 18 μg m−3 in the different sites. There were unexpected significant gradients in the concentrations of secondary aerosol components in length scales of a few hundred kilometers. The low concentrations of measured PM2.5 nitrate are mostly organic nitrates and supermicrometer nitrate associated with sea-salt and dust. Dust was a significant PM10 constituent in all areas and was quite variable in space showing the importance of the local sources. Keywords: PM2.5, sulfate aerosol, secondary inorganic aerosol, secondary organic aerosol, Greece Published in RUNG: 13.05.2024; Views: 475; Downloads: 0 This document has many files! More... |
133. Sources and processes that control the submicron organic aerosol composition in an urban Mediterranean environment (Athens) : a high temporal-resolution chemical composition measurement studyIasonas Stavroulas, Aikaterini Bougiatioti, Georgios Grivas, D. Paraskevopoulou, M. Tsagkaraki, Pavlos Zarmpas, Eleni Liakakou, Evangelos Gerasopoulos, Nikolaos Mihalopoulos, 2019, original scientific article Abstract: Submicron aerosol chemical composition was studied during a year-long
period (26 July 2016–31 July 2017) and two wintertime intensive campaigns
(18 December 2013–21 February 2014 and 23 December 2015–17 February 2016),
at a central site in Athens, Greece, using an Aerosol Chemical Speciation
Monitor (ACSM). Concurrent measurements included a particle-into-liquid
sampler (PILS-IC), a scanning mobility particle sizer (SMPS), an AE-33
Aethalometer, and ion chromatography analysis on 24 or 12 h filter samples.
The aim of the study was to characterize the seasonal variability of the main
submicron aerosol constituents and decipher the sources of organic aerosol
(OA). Organics were found to contribute almost half of the submicron mass,
with 30 min resolution concentrations during wintertime reaching up to
200 µg m−3. During winter (all three campaigns combined),
primary sources contributed about 33 % of the organic fraction, and comprised
biomass burning (10 %), fossil fuel combustion (13 %), and cooking
(10 %), while the remaining 67 % was attributed to secondary aerosol.
The semi-volatile component of the oxidized organic aerosol (SV-OOA;
22 %) was found to be clearly linked to combustion sources, in
particular biomass burning; part of the very oxidized,
low-volatility component (LV-OOA; 44 %) could also be attributed to the
oxidation of emissions from these primary combustion sources. These results, based on the combined contribution of biomass burning organic
aerosol (BBOA) and SV-OOA, indicate the importance of increased biomass
burning in the urban environment of Athens as a result of the economic recession.
During summer, when concentrations of fine aerosols are considerably lower,
more than 80 % of the organic fraction is attributed to secondary aerosol
(SV-OOA 31 % and LV-OOA 53 %). In contrast to winter, SV-OOA appears
to result from a well-mixed type of aerosol that is linked to fast photochemical
processes and the oxidation of primary traffic and biogenic emissions.
Finally, LV-OOA presents a more regional character in summer, owing to the
oxidation of OA over the period of a few days. Keywords: ACSM, organic aerosol, PMF, source apportionment Published in RUNG: 13.05.2024; Views: 475; Downloads: 4
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134. Applicability of benchtop multi-wavelength polar photometers to off-line measurements of the Multi-Angle Absorption Photometer (MAAP) samplesSara Valentini, Vera Bernardoni, Ezio Bolzacchini, Davide Ciniglia, Luca Ferrero, Alice Corina Forello, Dario Massabò, Marco Pandolfi, Paolo Prati, Jesús Yus-Díez, 2021, original scientific article Keywords: aerosol absorption coefficient, equivalent black carbon, MAAP, polar photometer, multi-wavelength Published in RUNG: 13.05.2024; Views: 479; Downloads: 1
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135. Regional new particle formation as modulators of cloud condensation nuclei and cloud droplet number in the eastern MediterraneanPanayiotis Kalkavouras, Aikaterini Bougiatioti, Nikos Kalivitis, Iasonas Stavroulas, Maria Tombrou, Athanasios Nenes, Nikolaos Mihalopoulos, 2019, original scientific article Abstract: A significant fraction of atmospheric particles that serve as cloud
condensation nuclei (CCN) are thought to originate from the condensational
growth of new particle formation (NPF) from the gas phase. Here, 7 years of
continuous aerosol and meteorological measurements (June 2008 to May 2015)
at a remote background site of the eastern Mediterranean were recorded and
analyzed to assess the impact of NPF (of 162 episodes identified) on CCN and
cloud droplet number concentration (CDNC) formation in the region. A new
metric is introduced to quantitatively determine the initiation and duration
of the influence of NPF on the CCN spectrum. NPF days were found to increase
CCN concentrations (from 0.10 % to 1.00 % supersaturation) between 29 %
and 77 %. Enhanced CCN concentrations from NPF are mostly observed, as
expected, under low preexisting particle concentrations and occur in the
afternoon, relatively later in the winter and autumn than in the summer.
Potential impacts of NPF on cloud formation were quantified by introducing
the observed aerosol size distributions and chemical composition into an
established cloud droplet parameterization. We find that the
supersaturations that develop are very low (ranging between 0.03 % and
0.27 %) for typical boundary layer dynamics (σw
∼0.3 m s−1) and NPF is found to enhance CDNC by a modest
13 %. This considerable contrast between CCN and CDNC response is in part
from the different supersaturation levels considered, but also because
supersaturation drops from increasing CCN because of water vapor competition
effects during the process of droplet formation. The low cloud
supersaturation further delays the appearance of NPF impacts on CDNC to
clouds formed in the late evening and nighttime – which has important
implications for the extent and types of indirect effects induced by NPF
events. An analysis based on CCN concentrations using prescribed
supersaturation can provide very different, even misleading, conclusions and
should therefore be avoided. The proposed approach here offers a simple, yet
highly effective way for a more realistic impact assessment of NPF events on
cloud formation. Keywords: regional NPF, CCN, cloud droplets, Eastern Mediterranean, regional background Published in RUNG: 13.05.2024; Views: 517; Downloads: 4
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136. Particle number size distribution statistics at City-Centre Urban Background, urban background, and remote stations in Greece during summerS. Vratolis, Maria I. Gini, Spiros Bezantakos, Iasonas Stavroulas, Nikos Kalivitis, E. Kostenidou, E. Louvaris, D. Siakavaras, George Biskos, Nikolaos Mihalopoulos, 2019, original scientific article Abstract: Particle number size distribution measurements were conducted during the summer of 2012 at City-Centre Urban Background (Patras-C), Urban Background (ICE-HT in Patras, DEM in Athens, EPT in Thessaloniki), and Regional Background stations (FIN in Crete). At the City-Centre Urban Background station, the average number distribution had a geometric mean diameter peak approximately at 60 nm and the highest number concentration, whereas at the Regional Background station and the Urban Background stations it displayed a major peak approximately at 100 nm, with the Regional Background station exhibiting the lowest number concentration. The particle number size distribution at each site was divided into size fractions and, based on their diurnal variation and previous studies, we concluded that the main sources for the City-Centre Urban Background station are traffic and the regional background concentration, for the Urban Background stations fresh traffic, aged traffic, cooking and the regional background concentration, and for the Regional Background station local activities (tourism, cooking) and regional background concentration. The median number concentration that is attributed to regional background concentration for the City-Centre Urban Background, the Urban Background and the Regional Background stations are respectively 13, 29 and 45% of the total number concentration. Nucleation events were identified at DEM station, where the newly formed particles accounted for 4% of the total particle concentration for the measurement period in the size range 10–20 nm, EPT, where they accounted for 12%, and FIN, where they accounted for 1%, respectively. New Particle Formation events contribution during summer to Condensation Cloud Nuclei were therefore insignificant in the Eastern Mediterranean. Modal analysis was performed on the number distributions and the results were classified in clusters. At the City-Centre Urban Background station, the cluster-source that dominated number concentration and frequency is related to fresh and aged traffic emissions, at the Urban Background stations aged traffic emissions, while at the Regional Background station number and frequency were dominated by the regional background concentration. Based on cluster analysis, 18% of the median number distribution was due to long range transport at the City-Centre Urban Background site, 37% at the Urban Background sites, and 59% at the Regional Background site. The Flexible Particle Dispersion Model (FLEXPART) was used in order to acquire geographic origin clusters and we concluded that the Etesian flow increases the median regional background number concentration in the Mediterranean basin by a factor of 2.5–4. Keywords: Mediterranean aerosol, particle number size distribution clustering, FLEXPART clustering Published in RUNG: 13.05.2024; Views: 486; Downloads: 0 This document has many files! More... |
137. Optical properties of near-surface urban aerosols and their chemical tracing in a Mediterranean city (Athens)Dimitris Katsanos, Aikaterini Bougiatioti, Eleni Liakakou, Dimitris G. Kaskaoutis, Iasonas Stavroulas, D. Paraskevopoulou, Maria Lianou, Basil E. Psiloglou, Evangelos Gerasopoulos, Christodoulos Pilinis, 2019, original scientific article Abstract: One-year measurements (October 2016–September 2017) of aerosol optical properties in the Athens urban environment were analyzed; for closure purposes, the results were supported by data of chemical composition of the non-refractory submicron aerosol fraction acquired with an Aerosol Chemical Speciation Monitor (ACSM). Both the spectral scattering (bsca) and absorption (babs) coefficients exhibit a pronounced annual variability with higher values (63.6 Mm–1 at 550 nm and 41.0 Mm–1 at 520 nm, respectively) in winter, due to domestic heating releasing increased carbonaceous emissions and the shallow mixing layer trapping aerosols near the surface. Much lower values (33.5 Mm–1 and 22.9 Mm–1 for bsca and babs, respectively) are found during summer, indicating rather aged aerosols from regional sources. The estimations of the dry spectral single scattering albedo (SSA), scattering (SAE) and absorption (AAE) Ångström exponents focus on the seasonality of the urban aerosols. The high SAE (~2.0) and low SSA (0.62 ± 0.11) values throughout the year indicate the dominance of fine-absorbing aerosols from fossil-fuel combustion, while the high AAE (~1.5) in winter suggests enhanced presence of biomass-burning aerosols. Pronounced morning and late evening/night peaks are found in both bsca and babs during winter, coinciding with the morning traffic rush hour and increased residential wood burning in the evening, while in the other seasons, the diurnal patterns flatten out. The wind speed strongly affects the aerosol loading and properties in winter, since for winds below 3 m s–1, a high increase in bsca and babs is observed, consistent with low dilution processes and hazy/smoggy conditions. Our closure experiments indicate a good agreement (R2 = 0.91, slope = 1.08) between the reconstructed and measured bsca values and reveal that organic matter contributes about half of the sub-micron mass in winter, followed by sulfate (~40%) and nitrate (10%, only in winter) aerosols. Keywords: urban aerosols, light scattering, absorption, chemical species, wood burning, Athens Published in RUNG: 10.05.2024; Views: 486; Downloads: 4
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138. Measurement of atmospheric black carbon in some South Mediterranean cities : seasonal variations and source apportionmentHamza Merabet, Rabah Kerbachi, Nikolaos Mihalopoulos, Iasonas Stavroulas, Maria Kanakidou, Noureddine Yassaa, 2019, original scientific article Abstract: This study aims to investigate, for the first time in Algeria, the atmospheric black carbon (BC) concentrations over one year measured at the Scientific Observatory of Algiers and to compare their concentration levels with other Mediterranean cities (i.e., Athens and Crete). The diurnal cycles as well as seasonal variations of BC concentrations were evaluated and attributed to their emission sources (fossil fuel: BCff and wood burning: BCwb). The annual mean concentrations of BC, BCff and BCwb were 1.113±2.030, 1.064±2.002 and 0.049±0.262 µgm-3, respectively. The highest seasonal mean concentrations were recorded in summer and autumn with 1.283±1.346 and 1.209±1.149 µgm-3 for BC and 1.217±1.431 and 1.177±1.151 µgm-3 for BCff, respectively. However, the lowest mean concentrations were recorded in winter and spring with 1.023±1.189 and 0.966±0.964 µgm-3 for BC and 0.933±1.177 and 0.956±0.874 µgm-3 for BCff, respectively. For BCwb, the highest mean concentrations were reached in winter and summer with 0.090±0.055 and 0.066±0.050 µgm-3, respectively, very likely due to the forest fires and long-range transport of air pollution from Europe. The lowest mean concentrations of BCwb were recorded in autumn and spring with 0.032±0.033 and 0.010±0.021 µgm-3, respectively. Seggregating BC levels into eight wind sectors, showed that the prevailing BC pollution with concentrations reaching up to 5.000 µgm-3 originated from the North-West wind sector. A source apportionment of BC for the wet and dry period was also perfomed followed by a back trajectory cluster analysis for long-range transport. Keywords: aerosol, black carbon, atmospheric pollution, source apportionment, seasonal variation, year modulation Published in RUNG: 10.05.2024; Views: 470; Downloads: 4
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139. Measuring the spatial variability of black carbon in Athens during wintertimeGeorgios Grivas, Iasonas Stavroulas, Eleni Liakakou, Dimitris G. Kaskaoutis, Aikaterini Bougiatioti, D. Paraskevopoulou, Evangelos Gerasopoulos, Nikolaos Mihalopoulos, 2019, original scientific article Abstract: A first assessment of the spatial variability of ambient black carbon (BC) concentrations in the Greater Area of Athens (GAA) was carried out during an intensive wintertime campaign, when ambient levels are exacerbated by increased biomass burning for residential heating. Short-term daytime BC measurements were conducted at 50 sites (traffic and urban/suburban/regional background) and on-road along 12 routes. Daytime measurements were adjusted based on BC concentrations continuously monitored at a reference site. Indicative nighttime BC ambient concentrations were also measured at several residences across the area. Daytime BC concentrations recorded an average of 2.3 μg m-3 with considerable between-site variability. Concentrations at traffic sites were significantly higher (43% on average), compared with the rest of the sites. Varying levels were observed between background site subtypes, with concentrations at urban background sites (located near the center of Athens and the port of Piraeus) being 34% and 114% higher, on average, than at suburban and regional background sites, respectively. The traffic intensity at the nearest road and the population and built density in the surrounding area of sites were recognized as important factors controlling BC levels. On-road concentration measurements (5.4 μg m-3 on average) enabled the identification of hot-spots in the road network, with peak levels encountered along motorways (13.5 μg m-3 on average). Nighttime measurements demonstrated that wintertime BC pollution, enhanced by residential biomass burning for heating, affects the entire Athens basin. The reference site in central Athens was found to be representative of the temporal variability for daytime and nighttime BC concentrations at background locations. Keywords: mobile measurements, microaethalometer, Athens, mapping, traffic, biomass burning Published in RUNG: 10.05.2024; Views: 456; Downloads: 5
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140. Yearlong measurements of monoterpenes and isoprene in a Mediterranean city (Athens) : natural vs anthropogenic originAnastasia Panopoulou, Eleni Liakakou, Stéphane Sauvage, Valérie Gros, Nadine Locoge, Iasonas Stavroulas, Bernard Bonsang, Evangelos Gerasopoulos, Nikolaos Mihalopoulos, 2020, original scientific article Abstract: Monoterpenes and isoprene are important constituents of the volatile organic compounds (VOCs) due to their high reactivity and participation in ozone and secondary aerosol formation. The current work focuses on the results of a 13-month intensive campaign of high resolution time-resolved measurements of these compounds, at an urban background site in Athens, Greece. On an annual basis, monoterpenes (α-pinene and limonene) surpass the isoprene levels presenting mean values of 0.70 ± 0.83 μg m−3, 0.33 ± 0.78 μg m−3 and 0.19 ± 0.36 μg m−3, respectively. The large standard deviation highlights the significant diurnal and day-to-day variability. Isoprene presents a typical seasonal cycle, with a photochemically induced summer-time maximum. Enhanced noon levels are observed during summer, whereas a morning peak in the autumn and winter profiles occurs, despite the generally low levels encountered during these seasons. The monoterpenes deviate from the expected biogenic pattern, presenting higher mean levels during the cold period and a night-to-early morning enhancement strongly related to local anthropogenic tracers such as BC, CO, NO or toluene, as well as increased levels under wind speeds lower than 3 m s−1. Estimations of the anthropogenic and biogenic fractions based on the enhancement ratios of α-pinene versus a variety of anthropogenic tracers, demonstrate a clear dominance of the anthropogenic sources in all studied seasons. Simultaneously, the biogenic fraction increased during summer relative to winter by more than 10 times. Both α-pinene and limonene significantly contribute to locally formed secondary organic aerosol (SOA), determined by means of an ACSM, accounting for at least 22% and 13% of their levels in summer and winter respectively. Additionally, monoterpenes and isoprene contribute 6% to the observed oxidants levels (O3 + NOx) during summer. Keywords: volatile organic compounds, biogenic compounds, monoterpenes, isoprene, Athens Published in RUNG: 10.05.2024; Views: 468; Downloads: 2
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