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Abstract: We use the surface detector of the Pierre Auger Observatory to search for air showers initiated by photons with an energy above 10[sup]19 eV. Photons in the zenith angle range from 30 deg. to 60 deg. can be identified in the overwhelming background of showers initiated by charged cosmic rays through the broader time structure of the signals induced in the water-Cherenkov detectors of the array and the steeper lateral distribution of shower particles reaching ground. Applying the search method to data collected between January 2004 and June 2020, upper limits at 95% CL are set to an E[sup]-2 diffuse flux of ultra-high energy photons above 10[sup]19 eV, 2 × 10[sup]19 eV and 4 × 10[sup]19 eV amounting to 2.11 × 10[sup]-3, 3.12 × 10[sup]-4 and 1.72 × 10[sup]-4 km-2 sr-1 yr-1, respectively. While the sensitivity of the present search around 2 × 10[sup]19 eV approaches expectations of cosmogenic photon fluxes in the case of a pure-proton composition, it is one order of magnitude above those from more realistic mixed-composition models. The inferred limits have also implications for the search of super-heavy dark matter that are discussed and illustrated.
Keywords: ultra-high-energy cosmic rays, UHE photons, Pierre Auger Observatory, extensive air showers, water Cherenkov detectors
Published in RUNG: 18.08.2023; Views: 906; Downloads: 12
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Keywords: Magnetic catalyst, Photocatalyst, Water treatment, Sunlight, Contaminants of emerging concern, Photo-Fenton-like systems, Cu, Mn, Fe, XANES, EXAFS
Published in RUNG: 06.07.2023; Views: 1460; Downloads: 5
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Abstract: Strategies to generate high-valence metal species capable of oxidizing water often employ composition and coordination tuning of oxide-based catalysts, where strong covalent interactions with metal sites are crucial. However, it remains unexplored whether a relatively weak “non-bonding” interaction between ligands and oxides can mediate the electronic states of metal sites in oxides. Here we present an unusual non-covalent phenanthroline-CoO2 interaction that substantially elevates the population of Co4+ sites for improved water oxidation. We find that phenanthroline only coordinates with Co2+ forming soluble Co(phenanthroline)2(OH)2 complex in alkaline electrolytes, which can be deposited as amorphous CoOxHy film containing non-bonding phenanthroline upon oxidation of Co2+ to Co3+/4+. This in situ deposited catalyst demonstrates a low overpotential of 216 mV at 10 mA cm−2 and sustainable activity over 1600 h with Faradaic efficiency above 97%. Density functional theory calculations reveal that the presence of phenanthroline can stabilize CoO2 through the non-covalent interaction and generate polaron-like electronic states at the Co-Co center.
Keywords: water oxidation, cobalt hydroxide, ligand-metal interactions
Published in RUNG: 23.02.2023; Views: 1716; Downloads: 15
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Keywords: Iron phosphide thin films H2 generation water remediation
Published in RUNG: 10.02.2023; Views: 1214; Downloads: 0
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Abstract: The effect of different water matrices on the photocatalytic degradation of dissolved pharmaceuticals was explored. The focus was on the degradation efficiencies in wastewater effluent from a bioreactor and water effluent from a central wastewater treatment plant and comparing the results with degradation in deionized H2O. The compounds tested included: oxytetracycline, marbofloxacin, ibuprofen, diclofenac, phenytoin, ciprofloxacin, sulfamethoxazole. For the experiments performed in this study, a compact packed-bed photocatalytic reactor was used in which the hybrid TiO2 photocatalyst (sol-gel/P25) was deposited on ~3 mm glass beads. As expected, the reactions proceed more slowly in wastewater than in deionized water, yet it is shown that removal of the compounds from the water is still possible even when other organic molecules are present. Total organic carbon measurements have shown that complete mineralization takes place albeit at slower rates than the initial degradation of parent compounds. The results show that an acidic pH can increase the reaction rates and the adsorption on the photocatalyst surface. Analyses of the degradation intermediates were performed using tandem liquid chromatography triple-quadrupole mass spectrometry system. Additionally, X-ray absorption spectroscopy was applied to get insight into the local structure of the photocatalyst before and after use. Understanding the effects that different wastewater compositions have on photocatalytic reactions will help to refine the potential applications of the technology.
Keywords: titanium dioxide, sol-gel processes, functionla applications, water treatment
Published in RUNG: 30.09.2022; Views: 1478; Downloads: 0
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