1. Crystallizing covalent organic frameworks from metal organic framework through chemical induced-phase engineeringAbdul Khayum Mohammed, Safa Gaber, Jesus Raya, Tina Škorjanc, Nada Elmerhi, Sasi Stephen, Pilar Pena-Sánchez, Felipe Gándara, Steven Hinder, Mark A. Baker, Kyriaki Polychronopoulou, Dinesh Shetty, 2023, original scientific article Abstract: The ordered porous frameworks like MOFs and COFs are generally constructed using the monomers through distinctive metal-coordinated and covalent linkages. Meanwhile, the inter-structural transition between each class of these porous materials is an under-explored research area. However, such altered frameworks are expected to have exciting features compared to their pristine versions. Herein, we have demonstrated a chemical-induction phase-engineering strategy to transform a two dimensional conjugated Cu-based SA-MOF (Cu-Tp) into 2D-COFs (Cu-TpCOFs). The structural phase transition offered in-situ pore size engineering from 1.1 nm to 1.5–2.0 nm. Moreover, the Cu-TpCOFs showed uniform and low percentage-doped (~ 1–1.5%) metal distribution and improved crystallinity, porosity, and stability compared to the parent Cu-Tp MOF. The construction of a framework from another framework with new linkages opens interesting opportunities for phase-engineering.
Keywords: metal organic framework, covalent organic framework, phase engineering, chemical transformation, porous materials
Published in RUNG: 10.11.2023; Views: 4064; Downloads: 7
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2. Enzyme-immobilized hierarchically porous covalent organic framework biocomposite for catalytic degradation of broad-range emerging pollutants in waterNada Elmerhi, Khadega Al-Maqdi, Khawlah Athamneh, Abdul Khayum Mohammed, Tina Škorjanc, Felipe Gándara, Jesus Raya, Pascal Simon, Olivier Siri, Ali Trabolsi, 2023, original scientific article Abstract: Efficient enzyme immobilization is crucial for the successful commercialization of large-scale enzymatic water treatment.
However, issues such as lack of high enzyme loading coupled with enzyme leaching present challenges for the widespread adoption
of immobilized enzyme systems. The present study describes the development and bioremediation application of an enzyme
biocomposite employing a cationic macrocycle-based covalent organic framework (COF) with hierarchical porosity for the
immobilization of horseradish peroxidase (HRP). The intrinsic hierarchical porous features of the azacalix[4]arene-based COF
(ACA-COF) allowed for a maximum HRP loading capacity of 0.76 mg/mg COF with low enzyme leaching (<5.0%). The
biocomposite, HRP@ACA-COF, exhibited exceptional thermal stability (~200% higher relative activity than the free enzyme),
and maintained ~60% enzyme activity after five cycles. LCMSMS analyses confirmed that the HRP@ACA-COF system was able
to achieve >99% degradation of seven diverse types of emerging pollutants (2-mercaptobenzothiazole, paracetamol, caffeic acid,
methylparaben, furosemide, sulfamethoxazole, and salicylic acid)in under an hour. The described enzyme-COF system offers
promise for efficient wastewater bioremediation applications.
Keywords: covalent organic frameworks, enzymes, emerging pollutants, water purification, biocomposite
Published in RUNG: 11.08.2023; Views: 2830; Downloads: 11
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3. Covalent Organic Framework Based on Azacalix[4]arene for the Efficient Capture of Dialysis Waste ProductsTina Škorjanc, Dinesh Shetty, Felipe Gándara, Pascal Simon, Nawavi Naleem, Salma Abubakar, Liaqat Ali, Abdul Khayum Mohammed, Jesus Raya, Serdal Kirmizialtin, 2022, original scientific article Keywords: azacalixarene, covalent organic frameworks, dialysis, uric acid, creatinine, adsorption
Published in RUNG: 08.09.2022; Views: 3392; Downloads: 0
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4. Immobilization of Redox-Responsive Switches Into Calixarene-Based Covalent Organic Polymers for Environmental ApplicationsTina Skorjanc, Dinesh Shetty, Sudhir Kumar Sharma, Jesus Raya, Dong Suk Han, Ramesh Jagannathan, Ali Trabolsi, 2017, unpublished conference contribution Keywords: calixarene, redox switches, dye adsorption
Published in RUNG: 03.09.2020; Views: 3703; Downloads: 0
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5. Morphological diversity in nanoporous covalent organic materials derived from viologen and pyreneGobinda Das, Tina Škorjanc, Sudhir Kumar Sharma, Thirumurugan Prakasam, Carlos Platas-Iglesias, Dong Suk Han, Jesus Raya, John-Carl Olsen, Ramesh Jagannathan, Ali Trabolsi, original scientific article Keywords: covalent organic polymers, hollow tube, polymers, porous materials, iodine capture
Published in RUNG: 02.09.2020; Views: 4033; Downloads: 0
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6. Rapid and Efficient Removal of Perfluorooctanoic Acid from Water with Fluorine-Rich Calixarene-Based Porous PolymersDinesh Shetty, Ilma Jahovic, Tina Škorjanc, Turan Selman Erkal, Liaqat Ali, Jesus Raya, Zouhair Asfari, Mark Anthony Olson, Serdal Kirmizialntin, Ozgur Yazaydin, Ali Trabolsi, 2020, original scientific article Keywords: Perfluorooctanoic acid, calixarene, adsorption, covalent polymers
Published in RUNG: 02.09.2020; Views: 3974; Downloads: 0
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7. Fast and efficient removal of paraquat in water by porous polycalix [n] arenes (n= 4, 6, and 8)Dinesh Shetty, Sandra Boutros, Tina Škorjanc, Bikash Garai, Zouhair Asfari, Jesus Raya, Ali Trabolsi, 2020, original scientific article Keywords: paraquat, adsorption, calixarene, covalent polymers, water purification
Published in RUNG: 02.09.2020; Views: 3695; Downloads: 0
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8. Remarkably efficient removal of toxic bromate from drinking water with a porphyrin–viologen covalent organic frameworkTina Skorjanc, Dinesh Shetty, Felipe Gandara, Liaqat Ali, Jesus Raya, Gobinda Das, Mark Anthony Olson, Ali Trabolsi, 2020, original scientific article Keywords: bromate, covalent organic frameworks, Zincke reaction, porphyrin, water purification, viologen
Published in RUNG: 02.09.2020; Views: 4236; Downloads: 0
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