21. Molecular and physical characteristics of aerosol at a remote free troposphere site : implications for atmospheric agingSimeon K. Schum, Bo Zhang, Katja Džepina, Paulo Fialho, Claudio Mazzoleni, Lynn R. Mazzoleni, 2018, original scientific article Abstract: Aerosol properties are transformed by atmospheric processes during long-range transport and play a key role in the Earth’s radiative balance. To understand the molecular and physical characteristics of free tropospheric aerosol, we studied samples collected at the Pico Mountain Observatory in the North Atlantic. The observatory is located in the marine free troposphere at 2225m above sea level, on Pico Island in the Azores archipelago. The site is ideal for the study of long-range-transported free tropospheric aerosol with minimal local influence. Three aerosol samples with elevated organic carbon concentrations were selected for detailed analysis. FLEXPART retroplumes indicated that two
of the samples were influenced by North American wildfire
emissions transported in the free troposphere and one by
North American outflow mainly transported within the marine
boundary layer. Ultrahigh-resolution Fourier transform
ion cyclotron resonance mass spectrometry was used to determine
the detailed molecular composition of the samples.
Thousands of molecular formulas were assigned to each of
the individual samples. On average ~60% of the molecular
formulas contained only carbon, hydrogen, and oxygen
atoms (CHO), ~ 30% contained nitrogen (CHNO), and
~ 10% contained sulfur (CHOS). The molecular formula
compositions of the two wildfire-influenced aerosol samples
transported mainly in the free troposphere had relatively low
average O=C ratios (0:48 ± 0:13 and 0:45 ± 0:11) despite the
7–10 days of transport time according to FLEXPART. In contrast,
the molecular composition of the North American outflow
transported mainly in the boundary layer had a higher
average O=C ratio (0:57 ± 0:17) with 3 days of transport time.
To better understand the difference between free tropospheric
transport and boundary layer transport, the meteorological
conditions along the FLEXPART simulated transport pathways
were extracted from the Global Forecast System analysis
for the model grids. We used the extracted meteorological
conditions and the observed molecular chemistry to predict
the relative-humidity-dependent glass transition temperatures
(Tg) of the aerosol components. Comparisons of the
Tg to the ambient temperature indicated that a majority of
the organic aerosol components transported in the free troposphere were more viscous and therefore less susceptible to
oxidation than the organic aerosol components transported
in the boundary layer. Although the number of observations
is limited, the results suggest that biomass burning organic
aerosol injected into the free troposphere is more persistent
than organic aerosol in the boundary layer having broader
implications for aerosol aging.
Keywords: secondary organic aerosols, brown carbon, particle dispersion model, ultrahigh-resolution FT-ICR MS, Pico Mountain Observatory
Published in RUNG: 10.04.2021; Views: 3254; Downloads: 0
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22. Substantial brown carbon emissions from wintertime residential wood burning over FranceYunjiang Zhang, Alexandre Albinet, Jean-Eudes Petit, Véronique Jacob, Florie Chevrier, Gregory Gille, Sabrina Pontet, Eve Chrétien, Marta Dominik-Sègue, Gilles Levigoureux, Griša Močnik, Valérie Gros, Jean-Luc Jaffrezo, Olivier Favez, 2020, original scientific article Abstract: Brown carbon (BrC) is known to absorb light at subvisible wavelengths but its optical properties and sources are still poorly documented, leading to large uncertainties in climate studies. Here, we show its major wintertime contribution to total aerosol absorption at 370 nm (18–42%) at 9 different French sites. Moreover, an excellent correlation with levoglucosan (r2 = 0.9 and slope = 22.2 at 370 nm), suggesting important contribution of wood burning emissions to ambient BrC aerosols in France. At all sites, BrC peaks were mainly observed during late evening, linking to local intense residential wood burning during this time period. Furthermore, the geographic origin analysis also highlighted the high potential contribution of local and/or small-regional emissions to BrC. Focusing on the Paris region, twice higher BrC mass absorption efficiency value was obtained for less oxidized biomass burning organic aerosols (BBOA) compared to more oxidized BBOA (e.g., about 4.9 ± 0.2 vs. 2.0 ± 0.1 m2 g−1, respectively, at 370 nm). Finally, the BBOA direct radiative effect was found to be 40% higher when these two BBOA fractions are treated as light-absorbing species, compared to the non-absorbing BBOA scenario.
Keywords: Brown carbon, Multi sites, Residential wood burning, Mass absorption efficiency, France
Published in RUNG: 20.07.2020; Views: 4059; Downloads: 0
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23. Energy response of ISS-CREAM calorimeter with attenuation effectH.G. Zhang, Jon Paul Lundquist, 2020, other component parts Abstract: The NASA mission, Cosmic Ray Energetic And Mass experiment for the International Space Station (ISS-CREAM) is to measure individual cosmic-ray particle energy spectra from protons to iron nuclei, with an energy range from ~1 TeV to the so-called "knee", near 1015eV. Energies of cosmic-ray particles are measured from electromagnetic showers induced by particles in the calorimeter.
As a pioneer mission, the balloon-borne CREAM instrument has successfully flown seven times over the Antarctica for a cumulative exposure of 191 days. The CREAM calorimeter has shown sufficient capability to measure energies of cosmic-ray particles by capturing the electromagnetic shower profile within the interested energy range. The ISS-CREAM calorimeter is expected to have a similar performance and, before it was launched, an engineering-unit calorimeter was shipped to CERN for a full beam test. The full performance test includes position, energy, and angle scans of electron and pion beams together with a high voltage scan for calibration and characterization.
In addition to the regular analysis for performance test, we also applied an additional step to generate the universal energy responses by correcting the attenuation effect in the calorimeter readout. The general energy responses could be obtained after shifting the incident beam positions to a reference position near the center of the calorimeter, which provided improved energy resolutions. The result of this analysis will be used to determine the incident energies of the cosmic-ray particles in the flight data.
Keywords: cosmic rays, high-energy, particle physics, detectors
Published in RUNG: 29.04.2020; Views: 3968; Downloads: 185
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24. Conclusively Addressing the CoPc Electronic Structure: A Joint Gas- Phase and Solid-State Photoemission and Absorption Spectroscopy StudyTeng Zhang, I.E. Brumboiu, Valeria Lanzillotto, J. Lüder, C. Grazioli, Erika Giangrisostomi, R. Ovsyannikov, Y. Sassatelli, Ieva Bidermane, Monica de Simone, Marcello Coreno, Barbara Ressel, Matija Stupar, Maddalena Pedio, Petra Rudolf, Barbara Brena, Carla Puglia, 2017, original scientific article Keywords: Cobalt Phtalocyanine, photoemission spectroscopy, gas phase, solid state
Published in RUNG: 07.02.2018; Views: 5213; Downloads: 0
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25. Fast-Response Photonic Device Based on Organic-Crystal Heterojunctions Assembled into a Vertical-Yet-Open Asymmetric ArchitectureLei Zhang, Egon Pavlica, Zhong, Xiaolan, Liscio Fabiola, LI Songlin, Gvido Bratina, Orgiu Emanuele, Samori Paolo, 2017, original scientific article Keywords: organski polprevodniki, merjenja časa preleta, organski fotodetektorji
Published in RUNG: 24.01.2017; Views: 5048; Downloads: 0
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26. A nanomesh scaffold for supramolecular nanowire optoelectronic devicesLei Zhang, Egon Pavlica, Gvido Bratina, 2016, original scientific article Abstract: Supramolecular organic nanowires are ideal nanostructures for optoelectronics because they exhibit both efficient exciton generation as a result of their high absorption coefficient and remarkable light sensitivity due to the low number of grain boundaries and high surface-to-volume ratio. To harvest photocurrent directly from supramolecular nanowires it is necessary to wire them up with nanoelectrodes that possess different work functions. However, devising strategies that can connect multiple nanowires at the same time has been challenging. Here, we report a general approach to simultaneously integrate hundreds of supramolecular nanowires of N,N′-dioctyl-3,4,9,10-perylenedicarboximide (PTCDI-C8) in a hexagonal nanomesh scaffold with asymmetric nanoelectrodes. Optimized PTCDI-C8 nanowire photovoltaic devices exhibit a signal-to-noise ratio approaching 107, a photoresponse time as fast as 10 ns and an external quantum efficiency >55%. This nanomesh scaffold can also be used to investigate the fundamental mechanism of photoelectrical conversion in other low-dimensional semiconducting nanostructures.
Keywords: fotodetektor, organski polprevodnik, fotoprevodnost, organski kristal, elektronske komponente, nanožice
Published in RUNG: 05.10.2016; Views: 6253; Downloads: 0
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27. Compound specific isotope analysis of organophosphorus pesticidesPolonca Trebše, Langping Wu, Jun Yao, Ning Zhang, Hans H. Richnow, 2014, original scientific article Keywords: pesticidi, diklorvos, ometoat, dimetoat, CSIA
Published in RUNG: 16.06.2016; Views: 5328; Downloads: 20
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