1. A feasibility study of the use of reactive tracers to determine outdoor daytime OH radical concentrations within the urban environmentIain R. White, Damien Martin, K Fredrik Petersson, Stephen J Henshaw, Graham Nickless, Guy C Lloyd-Jones, Kevin C Clemitshaw, Dudley E Shallcross, 2014, original scientific article Abstract: Using a specifically designed chemical tracer to indirectly measure local atmospheric hydroxyl radical (OH) concentrations is a very appealing concept. Such a tracer will provide information on the amount of OH a tracer encounters, as it moves through the urban environment and provide a stringent test of models. However, to date an outdoor experiment such as this has not been conducted. This article discusses the reasons why this is so and examines the feasibility of using tracers to measure integrated urban OH levels over short (≤1km) distances. Keywords: reactive tracers, OH radicals, NO3 radicals, oxidising rate, dispersion, urban Published in RUNG: 18.07.2019; Views: 3733; Downloads: 0 This document has many files! More... |
2. Atmospheric chemistry and physics in the atmosphere of a developed megacity (London): An overview of the REPARTEE experiment and its conclusionsRoy M Harrison, Manuel DallOsto, David C S Beddows, Alistair J Thorpe, William J Bloss, James D Allan, Hugh Coe, James R Dorsey, Martin W Gallagher, Claire Martin, John Whitehead, Paul I Williams, Roderick L Jones, Justin M Langridge, A K Benton, Stephen M Ball, Ben Langford, C Nicholas Hewitt, Brian Davison, Damien Martin, K Fredrik Peterson, Stephen J Henshaw, Iain R. White, Dudley E Shallcross, Janet F Barlow, Tyrone Dunbar, Fay Davies, Eiko Nemitz, Gavin J Phillips, Carole Helfter, Chiara F Di Marco, Steven Smith, 2012, review article Abstract: The Regents Park and Tower Environmental Experiment (REPARTEE) comprised two campaigns in London in October 2006 and October/November 2007. The experiment design involved measurements at a heavily trafficked roadside site, two urban background sites and an elevated site at 160-190 m above ground on the BT Tower, supplemented in the second campaign by Doppler lidar measurements of atmospheric vertical structure. A wide range of measurements of airborne particle physical metrics and chemical composition were made as well as measurements of a considerable range of gas phase species and the fluxes of both particulate and gas phase substances. Significant findings include (a) demonstration of the evaporation of traffic-generated nanoparticles during both horizontal and vertical atmospheric transport; (b) generation of a large base of information on the fluxes of nanoparticles, accumulation mode particles and specific chemical components of the aerosol and a range of gas phase species, as well as the elucidation of key processes and comparison with emissions inventories; (c) quantification of vertical gradients in selected aerosol and trace gas species which has demonstrated the important role of regional transport in influencing concentrations of sulphate, nitrate and secondary organic compounds within the atmosphere of London; (d) generation of new data on the atmospheric structure and turbulence above London, including the estimation of mixed layer depths; (e) provision of new data on trace gas dispersion in the urban atmosphere through the release of purposeful tracers; (f) the determination of spatial differences in aerosol particle size distributions and their interpretation in terms of sources and physico-chemical transformations; (g) studies of the nocturnal oxidation of nitrogen oxides and of the diurnal behaviour of nitrate aerosol in the urban atmosphere, and (h) new information on the chemical composition and source apportionment of particulate matter size fractions in the atmosphere of London derived both from bulk chemical analysis and aerosol mass spectrometry with two instrument types. Keywords: megacity, trace gas, urban atmosphere, atmospheric transport, chemical composition, aerosol Published in RUNG: 18.07.2019; Views: 3989; Downloads: 0 This document has many files! More... |
3. Tracer concentration profiles measured in central London as part of the REPARTEE campaignDamien Martin, K Fredrik Petersson, Iain R. White, Stephen H Henshaw, Graham Nickless, Amy Lovelock, Janet F Barlow, Tyrone Dunbar, Curtis R Wood, Dudley E. Shallcross, 2011, original scientific article Abstract: There have been relatively few tracer experiments carried out that have looked at vertical plume spread in urban areas. In this paper we present results from two tracer (cyclic perfluorocarbon) experiments carried out in 2006 and 2007 in central London centred on the BT Tower as part of the REPARTEE (Regent's Park and Tower Environmental Experiment) campaign. The height of the tower gives a unique opportunity to study vertical dispersion profiles and transport times in central London. Vertical gradients are contrasted with the relevant Pasquill stability classes. Estimation of lateral advection and vertical mixing times are made and compared with previous measurements. Data are then compared with a simple operational dispersion model and contrasted with data taken in central London as part of the DAPPLE campaign. This correlates dosage with non-dimensionalised distance from source. Such analyses illustrate the feasibility of the use of these empirical correlations over these prescribed distances in central London. Keywords: advection, concentration (composition), dispersion, tracer, urban atmosphere, vertical mixing, vertical profile Published in RUNG: 18.07.2019; Views: 3935; Downloads: 0 This document has many files! More... |
4. Use of reactive tracers to determine ambient OH radical concentrations: Application within the indoor environmentIain R. White, Damien Martin, Maria Paz Muñoz, Fredrik K Petersson, Stephen J Henshaw, Graham Nickless, Guy C Lloyd-Jones, Keven C Clemitshaw, Dudley E. Shallcross, 2010, original scientific article Abstract: The hydroxyl radical (OH) plays a key role in determining indoor air quality. However, its highly reactive nature and low concentration indoors impede direct analysis. This paper describes the techniques used to indirectly quantify indoor OH, including the development of a new method based on the instantaneous release of chemical tracers into the air. This method was used to detect ambient OH in two indoor seminar rooms following tracer detection by gas chromatography- mass spectrometry (GCMS). The results from these tests add to the small number of experiments that have measured indoor OH which are discussed with regard to future directions within air quality research. Keywords: Ozone, Indoor air pollution, Indoor ozone, chemical tracers Published in RUNG: 18.07.2019; Views: 3672; Downloads: 0 This document has many files! More... |
5. CityFlux perfluorocarbon tracer experimentsFredrik K Petersson, Damien Martin, Iain R. White, Stephen J Henshaw, Graham Nickless, Ian Longley, Carl J Percival, Martin Gallagher, Dudley E. Shallcross, 2010, original scientific article Abstract: In June 2006, two perfluorocarbon tracer experiments were conducted in central Manchester UK as part of the CityFlux campaign. The main aim was to investigate vertical dispersion in an urban area during convective conditions, but dispersion mechanisms within the street network were also studied. Paired receptors were used in most cases where one receptor was located at ground level and one at roof level. One receptor was located on the roof of Portland Tower which is an 80m high building in central Manchester. Source receptor distances in the two experiments varied between 120 and 600 m. The results reveal that maximum concentration was sometimes found at roof level rather than at ground level implying the effectiveness of convective forces on dispersion. The degree of vertical dispersion was found to be dependent on source receptor distance as well as on building height in proximity to the release site. Evidence of flow channelling in a street canyon was also found. Both a Gaussian profile and a street network model were applied and the results show that the urban topography may lead to highly effective flow channelling which therefore may be a very important dispersion mechanism should the right meteorological conditions prevail. The experimental results from this campaign have also been compared with a simple urban dispersion model that was developed during the DAPPLE framework and show good agreement with this. The results presented here are some of the first published regarding vertical dispersion. More tracer experiments are needed in order to further characterise vertical concentration profiles and their dependence on, for instance, atmospheric stability. The impact of urban topography on pollutant dispersion is important to focus on in future tracer experiments in order to improve performance of models as well as for our understanding of the relationship between air quality and public health. Keywords: air quality, atmospheric chemistry, concentration (composition), convective system, dispersion, public health, street canyon, tracer, urban area Published in RUNG: 18.07.2019; Views: 3651; Downloads: 0 This document has many files! More... |