Coevaporation of doped inorganic carrier-selective layers for high-performance inverted planar perovskite solar cellsQiugui Zeng
, Zeyu Fan
, Beibei Zhang
, Yanbo Li
, Jiexuan Jiang
, Andraž Mavrič
, Nadiia Pastukhova
, Matjaž Valant
, 2022, original scientific article
Abstract: Inorganic carrier selective layers (CSLs), whose conductivity can be effectively tuned by doping, offer low-cost and stable alternatives for their organic counterparts in perovskite solar cells (PSCs). Herein, we employ a dual-source electron-beam co-evaporation method for the controlled deposition of copper-doped nickel oxide (Cu:NiO) and tungsten-doped niobium oxide (W:Nb2O5) as hole and electron transport layers, respectively. The mechanisms for the improved conductivity using dopants are investigated. Owing to the improved conductivity and optimized band alignment of the doped CSLs, the all-inorganic-CSLs-based PSCs achieves a maximum power conversion efficiency (PCE) of 20.47%. Furthermore, a thin titanium buffer layer is inserted between the W:Nb2O5 and the silver electrode to prevent the halide ingression and improve band alignment. This leads to a further improvement of PCE to 21.32% and a long-term stability (1200 h) after encapsulation. Finally, the large-scale applicability of the doped CSLs by co-evaporation is demonstrated for the device with 1 cm2 area showing a PCE of over 19%. Our results demonstrate the potential application of the co-evaporated CSLs with controlled doping in PSCs for commercialization.
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Summary of found: ...(PSCs). Herein, we employ a dual-source electron-beam co- evaporation method for the controlled deposition of copper-doped...
Keywords: carrier selective layers, Cu-doped nickel oxide, electron-beam evaporation, perovskite solar cells, W-doped niobium oxide
Published: 17.03.2022; Views: 609; Downloads: 13
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