1. Inference of the Mass Composition of Cosmic Rays with Energies from 10[sup]18.5 to 10[sup]20 eV Using the Pierre Auger Observatory and Deep LearningA. Abdul Halim, Andrej Filipčič, Jon Paul Lundquist, Shima Ujjani Shivashankara, Samo Stanič, Serguei Vorobiov, Danilo Zavrtanik, Marko Zavrtanik, 2025, original scientific article Abstract: We present measurements of the atmospheric depth of the shower maximum Xmax,
inferred for the first time on an event-by-event level using the Surface Detector
of the Pierre Auger Observatory. Using deep learning, we were able to extend
measurements of the Xmax distributions up to energies of 100 EeV (10[sup]20 eV),
not yet revealed by current measurements, providing new insights into the mass
composition of cosmic rays at extreme energies.
Gaining a 10-fold increase in statistics compared to the Fluorescence Detector data,
we find evidence that the rate of change of the average Xmax with the logarithm
of energy features three breaks at 6.5 ± 0.6 (stat) ± 1 (sys) EeV,
11 ± 2 (stat) ± 1 (sys) EeV, and 31 ± 5 (stat) ± 3 (sys) EeV, in the vicinity to the three
prominent features (ankle, instep, suppression) of the cosmic-ray flux.
The energy evolution of the mean and standard deviation of the measured Xmax
distributions indicates that the mass composition becomes increasingly heavier
and purer, thus being incompatible with a large fraction of light nuclei between
50 EeV and 100 EeV. Keywords: ultra-high-energy cosmic rays (UHECRs), extensive air showers, Pierre Auger Observatory, UHECR mass composition, depth of the shower maximum, fluorescence detector, surface detector, deep learning Published in RUNG: 20.01.2025; Views: 291; Downloads: 4
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2. Measurement of the depth of maximum of air-shower profiles with energies between ▫$10^{18.5} and 10^{20}$▫ eV using the surface detector of the Pierre Auger Observatory and deep learningA. Abdul Halim, P. Abreu, M. Aglietta, Andrej Filipčič, Jon Paul Lundquist, Shima Ujjani Shivashankara, Samo Stanič, Serguei Vorobiov, Danilo Zavrtanik, Marko Zavrtanik, 2025, original scientific article Abstract: We report an investigation of the mass composition of cosmic rays with energies
from 3 to 100 EeV (1 EeV = 10[sup]18 eV) using the distributions of the depth of shower
maximum Xmax. The analysis relies on ∼50,000 events recorded by the surface detector
of the Pierre Auger Observatory and a deep-learning-based reconstruction algorithm.
Above energies of 5 EeV, the dataset offers a 10-fold increase in statistics with respect to
fluorescence measurements at the Observatory. After cross-calibration using
the fluorescence detector, this enables the first measurement of the evolution of the mean
and the standard deviation of the Xmax distributions up to 100 EeV.
Our findings are threefold: (i) The evolution of the mean logarithmic mass toward a heavier
composition with increasing energy can be confirmed and is extended to 100 EeV.
(ii) The evolution of the fluctuations of Xmax toward a heavier and purer composition
with increasing energy can be confirmed with high statistics. We report a rather heavy
composition and small fluctuations in Xmax at the highest energies.
(iii) We find indications for a characteristic structure beyond a constant change
in the mean logarithmic mass, featuring three breaks that are observed in proximity
to the ankle, instep, and suppression features in the energy spectrum. Keywords: ultra-high-energy cosmic rays, UHECRs, extensive air showers, Pierre Auger Observatory, UHECR mass composition, depth of shower maximum, fluorescence detector, surface detector, deep learning Published in RUNG: 20.01.2025; Views: 301; Downloads: 4
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3. Combined fit of spectrum and composition for FR0 radio-galaxy-emitted ultra–high energy cosmic rays with resulting secondary photons and neutrinosJon Paul Lundquist, Serguei Vorobiov, Lukas Merten, Anita Reimer, Margot Boughelilba, Paolo Da Vela, Fabrizio Tavecchio, Giacomo Bonnoli, Chiara Righi, 2025, original scientific article Abstract: This study comprehensively investigates the gamma-ray dim population of Fanaroff–Riley
Type 0 (FR0) radio galaxies as potentially significant sources of ultra–high energy cosmic rays
(UHECRs, E > 10[sup]18 eV) detected on Earth. While individual FR0 luminosities are relatively
low compared to the more powerful Fanaroff–Riley Type 1 and Type 2 galaxies, FR0s are
substantially more prevalent in the local universe, outnumbering the more energetic galaxies
by a factor of ∼5 within a redshift of z ≤ 0.05. Employing CRPropa3 simulations, we estimate
the mass composition and energy spectra of UHECRs originating from FR0 galaxies for energies
above 10[sup]18.6 eV. This estimation fits data from the Pierre Auger Observatory (Auger)
using three extensive air shower models; both constant and energy-dependent observed
elemental fractions are considered. The simulation integrates an approximately isotropic
distribution of FR0 galaxies, extrapolated from observed characteristics, with UHECR
propagation in the intergalactic medium, incorporating various plausible configurations of
extragalactic magnetic fields, both random and structured. We then compare the resulting
emission spectral indices, rigidity cutoffs, and elemental fractions with recent Auger results.
In total, 25 combined energy-spectrum and mass-composition fits are considered. Beyond
the cosmic-ray fluxes emitted by FR0 galaxies, this study predicts the secondary photon and
neutrino fluxes from UHECR interactions with intergalactic cosmic photon backgrounds.
The multimessenger approach, encompassing observational data and theoretical models,
helps elucidate the contribution of low-luminosity FR0 radio galaxies to the total cosmic-ray
energy density. Keywords: ultra-high-energy cosmic rays, UHECRs, UHECR energy spectrum, Pierre Auger Observatory, UHECR mass composition, UHECR sources, extragalactic magnetic fields, UHECR propagation, CRPropa tool Published in RUNG: 06.01.2025; Views: 320; Downloads: 6
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4. Catalytic hydro(deoxy)genation of furfural and modelling of its reaction kinetics : dissertationRok Šivec, 2024, doctoral dissertation Abstract: In recent decades, there has been a growing interest in producing biofuels and biochemicals from renewable sources. Furfural stands as one of the ligno(hemi)cellulosic biomass derived platform chemical, which can be transformed into numerous value-added products.
The goal of this PhD was to systematically study hydrotreatment reactions of furfural under varying operating conditions and to gain insights into the reaction mechanism and kinetics. An extensive experimental and computational study of hydrogenation, hydrodeoxygenation, oligomerisation and etherification of furfural in a three-phase batch reactor was performed. The goals were divided into three consecutive objectives.
In the first part, hydrotreatment of furfural over Pd/C catalyst under various reaction conditions, including the solvent selection (solventless conditions, tetrahydrofuran, isopropanol), atmosphere (nitrogen, hydrogen), temperature (100–200 °C), pressure (25–75 bar) and stirring speed, was studied. A reaction pathway network and a micro-kinetic model were developed, incorporating thermodynamics (hydrogen solubility), mass transfer, adsorption, desorption, and surface reactions. These phenomena and their contribution to the surface coverages, TOF’s and global reaction rates were studied. The hydrogen presence on the catalyst surface was found to influence the main reaction pathway, leading to ring, aldehyde group or full hydrogenation.
In the second part, various monometallic catalysts (Pd/C, Pt/C, Re/C, Ru/C, Rh/C, Ni/C, Cu/C) were tested at 100 -200 °C with 60 bar of hydrogen and tetrahydrofuran as solvent. A generalized reaction pathway network was developed. H2 temperature-programmed reduction (H2-TPR) and CO temperature-programmed desorption (CO-TPD) were conducted, and a regression analysis of the results was subsequently performed by numerical modelling and optimisation. The obtained adsorption and desorption kinetic parameters for active metallic sites were further used in a generalized micro-kinetic model, applicable to all tested catalysts. Pd/C exhibited high activity and non-selective hydrogenation of furfural, while other catalysts showed selective aldehyde group hydrogenation followed by deoxygenation, consistent with density functional theory (DFT) calculations. Ru/C uniquely produced 2 methyltetrahydrofuran and ring-opening products at 200 °C. In silico optimization of reaction conditions for promising catalysts ((Pd/C, Pt/C, Re/C, Ni/C) aimed to maximize the yield of the target product.
In the third part, the influence of support on catalytic activity was studied. Hydrotreatment of furfural over Pd/Al2O3, Pd/SiO2, Ru/Al2O3, Ru/SiO2, Ni/Al2O3, and Ni/SiO2 was performed between 150 - 200 °C, using 60 bar of hydrogen and tetrahydrofuran as solvent. The strength and rate of adsorption and desorption to/from acidic, metallic and interface site structures were determined, using H2-TPR, CO-TPD and NH3-TPD and subsequent regression analysis of the results by numerical modelling and optimisation. The resulting parameters were sequentially used in the generalized micro-kinetic model to quantify the contribution of the active metal (Ni, Pd, or Ru), support (Al2O3 or SiO2), interphase sites and their relationship on catalyst activity and selectivity. Evaluation of morphological and structural characteristics, adsorption/desorption and intrinsic reaction kinetics has indicated that the coverage of acidic sites (on alumina or silica) facilitated yielding ring hydrogenation and inhibited deoxygenation, decarbonylation and cyclic compound opening. The rates for aromatics or aldehyde functional groups were, nonetheless, affected in a different order.
The used and developed methods and findings of this PhD offer useful guidelines for transforming furfural into high-value chemicals through catalytic hydrotreatment, with significant implications for future research and industrial applications. Keywords: lignocellulosic biomass, furfural, catalytic hydrogenation, micro-kinetic mass transfer model, reaction kinetics, first-principle methods, furfuryl alcohol, tetrahydrofurfuryl alcoholv, dissertations Published in RUNG: 08.11.2024; Views: 590; Downloads: 15
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5. Atmospheric black carbon in the metropolitan area of La Paz and El Alto, Bolivia: concentration levels and emission sourcesValeria Mardoñez-Balderrama, Griša Močnik, Marco Pandolfi, Robin L. Modini, Fernando Velarde, Laura Renzi, Angela Marinoni, Jean-Luc Jaffrezo, Isabel Moreno R., Diego Aliaga, 2024, original scientific article Abstract: Abstract. Black carbon (BC) is a major component of submicron particulate matter (PM), with significant health and climate impacts. Many cities in emerging countries lack comprehensive knowledge about BC emissions and exposure levels. This study investigates BC concentration levels, identifies its emission sources, and characterizes the optical properties of BC at urban background sites of the two largest high-altitude Bolivian cities: La Paz (LP) (3600 m above sea level) and El Alto (EA) (4050 m a.s.l.), where atmospheric oxygen levels and intense radiation may affect BC production. The study relies on concurrent measurements of equivalent black carbon (eBC), elemental carbon (EC), and refractory black carbon (rBC) and their comparison with analogous data collected at the nearby Chacaltaya Global Atmosphere Watch Station (5240 m a.s.l). The performance of two independent source apportionment techniques was compared: a bilinear model and a least-squares multilinear regression (MLR). Maximum eBC concentrations were observed during the local dry season (LP: eBC = 1.5 ± 1.6 µg m−3; EA: 1.9±2.0 µg m−3). While eBC concentrations are lower at the mountain station, daily transport from urban areas is evident. Average mass absorption cross sections of 6.6–8.2 m2 g−1 were found in the urban area at 637 nm. Both source apportionment methods exhibited a reasonable level of agreement in the contribution of biomass burning (BB) to absorption. The MLR method allowed the estimation of the contribution and the source-specific optical properties for multiple sources, including open waste burning. Keywords: black carbon, aerosol absorption, source apportionment, mass absorption cross-section Published in RUNG: 29.10.2024; Views: 582; Downloads: 0
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6. Expected performance of the Auger Radio DetectorFelix Schlüter, Andrej Filipčič, Jon Paul Lundquist, Samo Stanič, Serguei Vorobiov, Danilo Zavrtanik, Marko Zavrtanik, Lukas Zehrer, 2023, published scientific conference contribution Abstract: The Auger Radio Detector (RD) will increase the sky coverage and overall aperture for mass- sensitive measurements of ultra-high-energy cosmic rays with the Pierre Auger Observatory. The installation of over 1600 dual-polarized short aperiodic loaded loop antennas (SALLAs) on an area of about 3000 sq. km will enable the detection of highly inclined air showers via the emitted electromagnetic radiation in coincidence with the Auger water-Cherenkov detector array (SD). The combination of complementary information from both detectors yields a strong sensitivity to the mass composition of cosmic rays.
We will present the expected performance of the RD to detect and reconstruct inclined air showers. This study features comprehensive sets of Monte-Carlo generated air showers, utilizes a complete description of the instrumental response of the radio antennas, and in-situ recorded background. The estimation of an energy- and direction-dependent aperture yields an expectation of about 3900 events with energies above 10[sup]19 eV being detected during 10 years of operation. From a full event reconstruction, we quantify the achievable energy resolution to be better than 10% at and beyond 10[sup]19 eV. With this at hand, the potential to measure the number of muons and discriminate between different cosmic-ray primaries in combination with the SD using inclined air showers is presented. The discrimination between proton- and iron-induced air showers yields a figure-of-merit of 1.6. Keywords: Pierre Auger Observatory, ultra-high-energy cosmic rays, extensive air showers, Auger Radio Detector, Auger water-Cherenkov detector array, mass-sensitive UHECR measurements Published in RUNG: 03.10.2024; Views: 660; Downloads: 6
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7. The depth of the shower maximum of air showers measured with AERABjarni Pont, Andrej Filipčič, Jon Paul Lundquist, Samo Stanič, Serguei Vorobiov, Danilo Zavrtanik, Marko Zavrtanik, Lukas Zehrer, 2023, published scientific conference contribution Abstract: The Auger Engineering Radio Array (AERA) is an array of 153 radio antennas spanning an area of 17 sq. km, currently the largest of its kind, that probes the nature of ultra-high energy cosmic rays at energies around the transition from Galactic to extra-galactic origin. It measures the MHz radio emission of extensive air showers produced by cosmic rays hitting our atmosphere. The elemental composition of cosmic rays is a crucial piece of information in determining what the sources of cosmic rays are and how cosmic rays are accelerated. This composition can be obtained from the mass-sensitive parameter Xmax, the depth of the shower maximum. We reconstruct Xmax with a likelihood analysis by comparing the measured radio footprint on the ground to an ensemble of footprints from Monte-Carlo CORSIKA/CoREAS air shower simulations. We compare our Xmax reconstruction with fluorescence Xmax measurements on a per-event basis, a setup unique to the Pierre Auger Observatory, and show the methods to be compatible. Furthermore, we extensively validate our reconstruction by identifying and correcting for systematic uncertainties. We determine the resolution of our method as a function of energy and reach a precision better than 15 g/cm[sup]2 at the highest energies. With a bias-free set of around 600 showers, we find a light to light-mixed composition at energies between 10[sup]17.5 to 10[sup]18.8 eV, also in agreement with Auger fluorescence measurements. Keywords: Pierre Auger Observatory, ultra-high-energy cosmic rays, extensive air showers, UHECR mass composition Published in RUNG: 03.10.2024; Views: 603; Downloads: 5
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8. A European aerosol phenomenology - 7 : high-time resolution chemical characteristics of submicron particulate matter across EuropeM. Bressi, F. Cavalli, Jean-Philippe Putaud, R. Fröhlich, J. -E. Petit, W. Aas, M. Äijälä, A. Alastuey, J. D. Allan, M. Aurela, Iasonas Stavroulas, Marta Via, 2021, original scientific article Abstract: Similarities and differences in the submicron atmospheric aerosol chemical composition are analyzed from a unique set of measurements performed at 21 sites across Europe for at least one year. These sites are located between 35 and 62°N and 10° W – 26°E, and represent various types of settings (remote, coastal, rural, industrial, urban). Measurements were all carried out on-line with a 30-min time resolution using mass spectroscopy based instruments known as Aerosol Chemical Speciation Monitors (ACSM) and Aerosol Mass Spectrometers (AMS) and following common measurement guidelines. Data regarding organics, sulfate, nitrate and ammonium concentrations, as well as the sum of them called non-refractory submicron aerosol mass concentration ([NR-PM1]) are discussed. NR-PM1 concentrations generally increase from remote to urban sites. They are mostly larger in the mid-latitude band than in southern and northern Europe. On average, organics account for the major part (36–64%) of NR-PM1 followed by sulfate (12–44%) and nitrate (6–35%). The annual mean chemical composition of NR-PM1 at rural (or regional background) sites and urban background sites are very similar. Considering rural and regional background sites only, nitrate contribution is higher and sulfate contribution is lower in mid-latitude Europe compared to northern and southern Europe. Large seasonal variations in concentrations (μg/m³) of one or more components of NR-PM1 can be observed at all sites, as well as in the chemical composition of NR-PM1 (%) at most sites. Significant diel cycles in the contribution to [NR-PM1] of organics, sulfate, and nitrate can be observed at a majority of sites both in winter and summer. Early morning minima in organics in concomitance with maxima in nitrate are common features at regional and urban background sites. Daily variations are much smaller at a number of coastal and rural sites. Looking at NR-PM1 chemical composition as a function of NR-PM1 mass concentration reveals that although organics account for the major fraction of NR-PM1 at all concentration levels at most sites, nitrate contribution generally increases with NR-PM1 mass concentration and predominates when NR-PM1 mass concentrations exceed 40 μg/m³ at half of the sites. Keywords: aerosol, chemical composition, mass spectrometry, phenomenology Published in RUNG: 10.05.2024; Views: 1228; Downloads: 5
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9. Recommendations for reporting equivalent black carbon (eBC) mass concentrations based on long-term pan-European in-situ observationsMarjan Savadkoohi, Marco Pandolfi, Olivier Favez, Jean-Philippe Putaud, Konstantinos Eleftheriadis, Markus Fiebig, Philip Hopke, Paolo Laj, A. Wiedensohler, Griša Močnik, 2024, original scientific article Abstract: A reliable determination of equivalent black carbon (eBC) mass concentrations derived from filter absorption photometers (FAPs) measurements depends on the appropriate quantification of the mass absorption cross-section (MAC) for converting the absorption coefficient (babs) to eBC. This study investigates the spatial–temporal variability of the MAC obtained from simultaneous elemental carbon (EC) and babs measurements performed at 22 sites. We compared different methodologies for retrieving eBC integrating different options for calculating MAC including: locally derived, median value calculated from 22 sites, and site-specific rolling regression MAC. The eBC concentrations that underwent correction using these methods were identified as LeBC (local MAC), MeBC (median MAC), and ReBC (Rolling MAC) respectively. Pronounced differences (up to more than 50 %) were observed between eBC as directly provided by FAPs (NeBC; Nominal instrumental MAC) and ReBC due to the differences observed between the experimental and nominal MAC values. The median MAC was 7.8 ± 3.4 m2/g from 12 aethalometers at 880 nm, and 10.6 ± 4.7 m2/g from 10 MAAPs at 637 nm. The experimental MAC showed significant site and seasonal dependencies, with heterogeneous patterns between summer and winter in different regions. In addition, long-term trend analysis revealed statistically significant (s.s.) decreasing trends in EC. Interestingly, we showed that the corresponding corrected eBC trends are not independent of the way eBC is calculated due to the variability of MAC. NeBC and EC decreasing trends were consistent at sites with no significant trend in experimental MAC. Conversely, where MAC showed s.s. trend, the NeBC and EC trends were not consistent while ReBC concentration followed the same pattern as EC. These results underscore the importance of accounting for MAC variations when deriving eBC measurements from FAPs and emphasizes the necessity of incorporating EC observations to constrain the uncertainty associated with eBC. Keywords: equivalent black carbon, mass absorption cross-section, filter absorption photometers, elemental carbon, absorption, site specific MAC, rolling MAC Published in RUNG: 04.03.2024; Views: 1813; Downloads: 10
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10. Astrophysical interpretation of energy spectrum and mass composition of cosmic rays as measured at the Pierre Auger ObservatoryEleonora Guido, Andrej Filipčič, Jon Paul Lundquist, Shima Ujjani Shivashankara, Samo Stanič, Serguei Vorobiov, Danilo Zavrtanik, Marko Zavrtanik, 2023, published scientific conference contribution Abstract: The combined interpretation of the spectrum and composition measurements plays a key role in the quest for the origin of ultra-high-energy cosmic rays (UHECRs). The Pierre Auger Observatory, thanks to its huge exposure, provides the most precise measurement of the energy spectrum of UHECRs and the most reliable information on their composition, exploiting the distributions of the depth of maximum of the showers in the atmosphere. A combined fit of a simple astrophysical model of UHECR sources to the spectrum and mass composition measurements is used to evaluate the constraining power of the data measured by the Pierre Auger Observatory on the source properties. We find that our data across
the “ankle” feature are well reproduced if two extragalactic populations of sources are considered, one emitting a very soft spectrum which dominates the region below the ankle, and the other taking over at energies above the ankle, with an intermediate mixed composition, a hard spectrum and a low rigidity cutoff. Interestingly, similar results can also be obtained if the medium-mass contribution at lower energy is provided by an additional galactic component. Keywords: Pierre Auger Observatory, ultra-high energy cosmic rays, UHECR energy spectrum, UHECR mass composition Published in RUNG: 24.01.2024; Views: 2527; Downloads: 18
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