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1.
Crystallizing covalent organic frameworks from metal organic framework through chemical induced-phase engineering
Abdul Khayum Mohammed, Safa Gaber, Jesus Raya, Tina Škorjanc, Nada Elmerhi, Sasi Stephen, Pilar Pena-Sánchez, Felipe Gándara, Steven Hinder, Mark A. Baker, Kyriaki Polychronopoulou, Dinesh Shetty, 2023, original scientific article

Abstract: The ordered porous frameworks like MOFs and COFs are generally constructed using the monomers through distinctive metal-coordinated and covalent linkages. Meanwhile, the inter-structural transition between each class of these porous materials is an under-explored research area. However, such altered frameworks are expected to have exciting features compared to their pristine versions. Herein, we have demonstrated a chemical-induction phase-engineering strategy to transform a two dimensional conjugated Cu-based SA-MOF (Cu-Tp) into 2D-COFs (Cu-TpCOFs). The structural phase transition offered in-situ pore size engineering from 1.1 nm to 1.5–2.0 nm. Moreover, the Cu-TpCOFs showed uniform and low percentage-doped (~ 1–1.5%) metal distribution and improved crystallinity, porosity, and stability compared to the parent Cu-Tp MOF. The construction of a framework from another framework with new linkages opens interesting opportunities for phase-engineering.
Keywords: metal organic framework, covalent organic framework, phase engineering, chemical transformation, porous materials
Published in RUNG: 10.11.2023; Views: 836; Downloads: 5
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Cationic polymer thin films for electrochemical detection of bacteria
Tina Škorjanc, 2022, published scientific conference contribution abstract

Keywords: sensors, electrochemical impedance spectroscopy, porous materials, E. coli
Published in RUNG: 06.12.2022; Views: 1419; Downloads: 6
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5.
Natural precursor based hydrothermal synthesis of sodium carbide for reactor applications
Mohanachandran Nair Sindhu Swapna, 2017, original scientific article

Abstract: Carbides are a class of materials with high mechanical strength and refractory nature which finds a wide range of applications in industries and nuclear reactors. The existing synthesis methods of all types of carbides have problems in terms of use of toxic chemical precursors, high-cost, etc. Sodium carbide (Na2C2) which is an alkali metal carbide is the least explored one and also that there is no report of low-cost and low-temperature synthesis of sodium carbide using the eco-friendly, easily available natural precursors. In the present work, we report a simple low-cost, non-toxic hydrothermal synthesis of refractory sodium carbide using the natural precursor—Pandanus. The formation of sodium carbide along with boron carbide is evidenced by the structural and morphological characterizations. The sample thus synthesized is subjected to field emission scanning electron microscopy (FESEM), x-ray powder diffraction (XRD), ultraviolet (UV)—visible spectroscopy, Fourier transform infrared spectroscopy (FTIR), Raman, and photoluminescent (PL) spectroscopic techniques.
Keywords: sodium carbide, pandanus, hydrothermal synthesis, porous materials
Published in RUNG: 30.06.2022; Views: 2074; Downloads: 0
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