Search the repository

A+ | A- | | SLO | ENG

Abstract: In the last two decades, studies on organic molecules mimicking substances of fundamental importance in nature, like chlorophyll or hemoglobin, have attracted researchers’ attention. These molecules are building blocks for a family of materials also referred to as “organic semiconductors”. Such compounds can be implemented in numerous applications, ranging from data-storage to light harvesting. Some of their fundamental advantages include low cost, light weight, relatively easy engineering and mechanical flexibility, compatible with bending plastic substrates. In this thesis work we investigated the chemical, structural and electronic properties of cobalt phthalocyanines (CoPc). These molecules have promising applications in the field of magnetic data storage and spintronics in general, due to the ferromagnetic properties of the cobalt atom. Several techniques like photoemission core-level spectroscopy and valence band spectroscopy, together with X-ray absorption, have been used in order to determine the CoPc properties in gaseous phase, i.e. in the absence of interaction with the surrounding environment. Another set of experiments was devoted to the commissioning of the CITIUS time-resolved photoemission setup, that will be used in future studies of CoPc molecules on surfaces.
Found in: ključnih besedah
Summary of found: ...spectroscopy (PES), X-ray absorption spectroscopy (XAS), synchrotron radiation, laser, high order harmonic generation (HHG), time...
Keywords: Cobalt phthalocyanine (CoPc), photoemission spectroscopy (PES), X-ray absorption spectroscopy (XAS), synchrotron radiation, laser, high order harmonic generation (HHG), time resolved spectroscopy
Published: 29.09.2015; Views: 7806; Downloads: 272
Fulltext (2,96 MB)

Found in: ključnih besedah
Summary of found: ...dark matter theory, dark matter experiments, absorption, radiation, ...
Keywords: dark matter theory, dark matter experiments, absorption, radiation
Published: 09.05.2017; Views: 3077; Downloads: 20
Fulltext (0,00 KB)

Abstract: The cosmic microwave background radiation discovered by Penzias and Wilson in 1965, is considered one of the most important experimental evidences in favour of the Hot Big Bang standard cosmological model. This radiation provides an image of the Universe when it was about 380,000 years old and has a blackbody spectral distribution at temperature T=2.725±0.002 K, index of thermodynamic equilibrium with the mater in epoch when it was released. The cosmic background radiation presents anisotropies at level of 10 5 which provide valuable information about the origin and the evolution of the Universe. After the discovery of background radiation, tens of experiments have been performed to measure this radiation and its anisotropies. In 1992 the COBE satellite revolutionized cosmology by detecting temperature anisotropies for the first time. Launched on May 14, 2009, Planck is a European Space Agency mission designed to measure the CMB anisotropies with an accuracy set by fundamental astrophysical limits. To do this, Planck is imaging the whole sky with an unprecedented combination of sensitivity ( ΔT/T~2*10^-6), angular resolution (to 5’), and 9 frequency coverage (30 857 GHz). To reach these ambitious requirements, Planck uses an active cryogenic thermal system which cools the instruments to 0.1 K. The high sensitivity of the instrument and the cryogenic system makes the thermal systematic effects study of crucial importance to the scientific success. The thesis is divided into six chapters: 1. Chapter 1 explains the properties of the cosmic background radiation and its anisotropies; 2. Chapter 2 presents a short overview of the various experiments dedicated to the study of cosmic background radiation; 3. Chapter 3 describes the Planck mission, its instruments and its goals, in particular the Low Frequency Instrument (LFI) and its thermal structure; Chapter 4 discusses the analysis of the LFI thermal stability. This work was carried out in the Physics department at the University of Trieste, at the LFI Data Processing Centre located at INAF (Instituto Nazionale di AstroFisica) - OATS (Astronomical Observatory of Trieste); Chapter 5 presents the results of this analysis; in Chapter 6 conclusions are drawn and proposals for future work are discussed.
Found in: ključnih besedah
Summary of found: ...The cosmic microwave background radiation discovered by Penzias and Wilson in 1965,...
Keywords: Cosmic background radiation, CMB, Planck, satellite mission
Published: 24.01.2018; Views: 2562; Downloads: 102
Fulltext (23,33 MB)

Abstract: This work is primarily focused on application of standard first-principle computational approaches to model oxygen excess related point defects in amorphous silica. Atomic models with their respective electronic and optical properties are explored together with some conversion mechanisms between defect models. The first chapter overviews extensive literature about the already known properties of oxygen related defects. Second chapter briefly introduces main methods that have been used in this research, in particular Density Functional Theory (DFT) as energy and force engine with short description of minimal energy path (MEP) algorithm used for modeling chemical/migration reactions, GW approximation for charged electronic excitations (band structure) and Bethe-Salpeter Equation (BSE) for neutral excitations (optical absorption and excitonic structure including electron hole interaction). The third chapter is devoted to the presentation of results. Thanks to the calculation of optical properties of peroxy bridge (POL), a correlation has been found between structural disorder, specifically dihedral angle dispersion, and low coupling with light, which has been identified as main reason why no clear absorption bands have been assigned to the POL. Structure and stability of some other defects, like interstitial ozone molecule (ozonyl) and dioxasilirane (silicon analogy of dioxirane), have been studied. These defects are usually not considered as most important species, however their calculated formation energies are lower compared to some known defects, which indicates they might be present in silica. From a detailed study on possible reaction mechanisms, it has been found that ozonyl might be one of the most important intermediate steps for oxygen exchange reactions. Results also show that dioxasilirane can be spontaneously created during the interaction of oxygen with lone pair defects. By exploring different reactions between oxygen and pre-existing oxygen deficiency centers (ODCs), calculations predict two kinds of passivation behaviors: single-barrier reversible mechanisms with the formation of dioxasilirane-like groups, for which the network keeps the memory of the precursory lone pair defects, and single or multiple-barrier mechanisms, for which the network loses its memory, either because of the high reverse barrier or because of a reconstruction. Final part of this research has been devoted to experimental characterization of the response and tolerance of optical fibers loaded with oxygen under irradiation. These include experiments on commercial fiber along with canonical samples (Optical fibers developed with the intention of studying correlations between different fabrication parameters, dopant/impurity concentration and doping concentrations). Studied fibers also include rare-earth doped fibers.
Found in: ključnih besedah
Summary of found: ...oxygen deficiency centers, optical absorption, optical fibers, radiation induced attenuation....
Keywords: Silica, DFT, GW-approximation, Bethe-Salpeter equation, NEB, defect, oxygen, oxygen excess centers, oxygen deficiency centers, optical absorption, optical fibers, radiation induced attenuation.
Published: 07.05.2019; Views: 3257; Downloads: 182
Fulltext (13,18 MB)

Abstract: Binary bismuth chalcogenides, Bi2Se3 and Bi2Te3, have been extensively studied as reference topological insulators (TIs). These materials are bulk insulators with topological surface states (TSS) crossing the Fermi level. In contrast to conventional surface states of metals, the TSS are extremely robust against local modifications at the surface, such as adsorbed adatoms, localized defects or changes in the surface termination. This aspect makes the TIs attractive for applications in spintronics, plasmonics, quantum computing and catalysis. A theoretical model of charge transport by the TI surface states predicts that the TSS survive, provided that bonding at the metal/TI interface is weak. Ab-initio calculations have been done to understand the electronic properties of Au, Ni, Pt, Pd and graphene layers in a contact with Bi2Se3. These calculations showed that for Au and graphene the spin-momentum locking of TSS is maintained at the interface. In another theoretical study, Ag and Au thin layers on Bi2Se3 have been predicted to show a large Rashba splitting and a high spin polarization of the Ag quantum wells, providing a great potential for development of the spintronic devices. Finally, the calculations have foreseen that the presence of the robust TSS affects the adsorption properties of metals (Au bi-layer and clusters of Au, Ag, Cu, Pt, and Pd) supported on TI, in some cases resulting in the enhancement of the catalytic processes. Despite the fundamental importance of the metal/TI interfaces and a number of theoretical studies predicting exotic interfacial phenomena, the experimental knowledge about the metals on the TI surfaces is surprisingly limited, especially concerning combined study of morphology, growth mode, electronic and chemical properties. In order to exploit the predicted physical properties of such systems, it is especially important to extend the study above the diluted coverage regime and to understand what is the growth morphology of the metal on the TI surface, to what extent the metal overlayer interacts with the TI substrate, how the TSS change with the presence of the metal overlayer and what is the reactivity of the system at the different stages of the overlayer growth. Within this frame, we present a comprehensive surface sensitive study, of Au and Ag on Bi2Se3 by means of ARPES, XPS, SEM, LEED and XRD. The obtained results allow us to discuss the relation between electronic and physical properties at two of the most important model metal/TI interfaces
Found in: ključnih besedah
Keywords: topological insulator, electronic properties, synchrotron radiation
Published: 27.06.2019; Views: 2597; Downloads: 0
Fulltext (5,72 MB)