Dissecting Mott and charge-density wave dynamics in the photoinduced phase of 1T-TaS[sub]2Alberto Simoncig
, Matija Stupar
, Barbara Ressel
, Tanusree Saha
, Primož Rebernik Ribič
, Giovanni De Ninno
, 2021, original scientific article
Abstract: The two-dimensional transition-metal dichalcogenide 1T−TaS2 is a complex material standing out for its puzzling low temperature phase marked by signatures amenable to both Mott-insulating and charge-density wave states. Electronic Mott states, coupled to a lattice, respond to coherent optical excitations via a modulation of the lower (valence) Hubbard band. Such dynamics is driven by strong electron-phonon coupling and typically lasts for tens of picoseconds, mimicking coherent structural distortions. Instead, the response occurring at the much faster timescale, mainly dominated by electronic many-body effects, is still a matter of intense research. By performing time- and angle-resolved photoemission spectroscopy, we investigated the photoinduced phase of 1T−TaS2 and found out that its lower Hubbard band promptly reacts to coherent optical excitations by shifting its binding energy towards a slightly larger value. This process lasts for a time comparable to the optical pump pulse length, mirroring a transient change of the onsite Coulomb repulsion energy (U). Such an observation suggests that the correction to the bare value of U, ascribed to the phonon-mediated screening which slightly opposes the Hubbard repulsion, is lost within an interval of a few tens of femtoseconds and can be understood as a fingerprint of electronic states largely decoupled from the lattice. Additionally, these results enforce the hypothesis, envisaged in the current literature, that the transient photoinduced states belong to a sort of crossover phase instead of an equilibrium metallic one.
Found in: ključnih besedah
Summary of found: ...The two-dimensional transition-metal dichalcogenide 1T−TaS2 is a complex material standing...
Keywords: ultrafast phenomena, time resolved photoemission, strongly correlated systems, transition metal dichalcogenide
Published: 13.04.2021; Views: 1049; Downloads: 0
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