Title: | Solar-driven photocatalytic treatment of diclofenac using immobilized TiO2-based zeolite composites |
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Authors: | Kovacic, Marin (Author) Salaeh, Subhan (Author) Kušić, Hrvoje (Author) Suligoj, Andraz (Author) Kete, Marko (Author) Fanetti, Mattia (Author) Lavrenčič Štangar, Urška (Author) Dionysiou, Dionysios D. (Author) Lončarić Božić, Ana (Author) |
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Files: | This document has no files. This document may have a phisical copy in the library of the organization, check the status via COBISS.  |
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Language: | English |
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Work type: | Not categorized (r6) |
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Tipology: | 1.01 - Original Scientific Article |
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Organization: | UNG - University of Nova Gorica |
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Abstract: | The study is aimed at evaluating the potential of
immobilized TiO2-based zeolite composite for solar-driven
photocatalytic water treatment. In that purpose, TiO2-iron-exchanged
zeolite (FeZ) composite was prepared using commercial
Aeroxide TiO2 P25 and iron-exchanged zeolite of ZSM5
type, FeZ. The activity of TiO2-FeZ, immobilized on glass
support, was evaluated under solar irradiation for removal of
diclofenac (DCF) in water. TiO2-FeZ immobilized in a form
of thin film was characterized for its morphology, structure,
and composition using scanning electron microscopy/energydispersive
x-ray spectroscopy (SEM/EDX). Diffuse reflectance
spectroscopy (DRS) was used to determine potential
changes in band gaps of prepared TiO2-FeZ in comparison
to pure TiO2. The influence of pH, concentration of hydrogen
peroxide, FeZ wt% within the composite, and photocatalyst
dosage on DCF removal and conversion efficiency by solar/
TiO2-FeZ/H2O2 process was investigated. TiO2-FeZ demonstrated
higher photocatalytic activity than pure TiO2 under
solar irradiation in acidic conditions and presence of H2O2. |
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Keywords: | Photocatalysis, Thin films, TiO2-FeZ, Solar irradiation, Diclofenac, Water Treatment |
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Year of publishing: | 2016 |
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Number of pages: | 13 |
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Numbering: | 23 |
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COBISS_ID: | 4445947  |
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URN: | URN:SI:UNG:REP:GEROLT9U |
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DOI: | 10.1007/s11356-016-6985-6  |
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Views: | 5169 |
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Downloads: | 0 |
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