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Title:Phase behaviour of self-assembled monolayers controlled by tuning physisorbed and chemisorbed states: a lattice-model view
Authors:ID Fortuna, Sara (Author)
ID Cheung, David L. (Author)
ID Johnston, Karen (Author)
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Language:English
Work type:Not categorized
Typology:1.01 - Original Scientific Article
Organization:UNG - University of Nova Gorica
Abstract:The self-assembly of molecules on surfaces into 2D structures is important for the bottom-up fabrication of functional nanomaterials, and the self-assembledstructure depends on the interplay between molecule-molecule interactions and molecule-surface interactions. Halogenated benzene derivatives on platinum have been shown to have two distinct adsorption states: a physisorbed state and a chemisorbed state, and the interplay between the two can be expected to have a profound effect on the self-assembly and phase behaviour of these systems. We developed a lattice model that explicitly includes both adsorption states, with representative interactions parameterised using density functional theory calculations. This model was used in Monte Carlo simulations to investigate pattern formation of hexahalogenated benzene molecules on the platinumsurface. Molecules that prefer the physisorbed state were found to self-assemble with ease, depending on the interactions between physisorbed molecules. In contrast, molecules that preferentially chemisorb tend to get arrested in disordered phases. However, changing the interactions between chemisorbed and physisorbed molecules affects the phase behaviour. We propose functionalising molecules in order to tune their adsorption states, as an innovative way to control monolayer structure, leading to a promising avenue for directed assembly of novel 2D structures.
Keywords:lattice model, hexagonal lattice, Monte Carlo, DFT, density functional theory, benzene, physisorption, chemisorption, halogenated
Year of publishing:2016
Number of pages:9
Numbering:144, 13
PID:20.500.12556/RUNG-2694 New window
COBISS.SI-ID:4534523 New window
DOI:10.1063/1.4944936 New window
NUK URN:URN:SI:UNG:REP:ZUUWO47M
Publication date in RUNG:11.10.2016
Views:4854
Downloads:0
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Record is a part of a journal

Title:Journal of Chemical Physics
Shortened title:J. Chem. Phys.
Publisher:AIP Publishing
Year of publishing:2016
ISSN:0021-9606

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