| Title: | Determination of Dissolved Iron Redox Species in Freshwater Sediment using DGT Technique Coupled to BDS |
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| Authors: | Budasheva, Hanna (Author)
Kravos, Aleksander (Author)
Korte, Dorota (Author)
Bratkič, Arne (Author)
Gao, Yue (Author)
Franko, Mladen (Author)
et al. |
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| Files: |  4848-33735-1-PB.pdf (452,58 KB)
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| Language: | English |
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| Work type: | Not categorized (r6) |
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| Tipology: | 1.01 - Original Scientific Article |
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| Organization: | UNG - University of Nova Gorica |
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| Abstract: | In this work we have developed a novel method for determination of iron redox species by the use of diffusive gradients in thin-film (DGT) technique coupled to photothermal beam deflection spectroscopy (BDS). The combination of both methods achieved low limit of detection (LOD) of 0.14 μM for Fe (II) ions. The total Fe concentration determined in the Vrtojbica river sediment (Slovenia, Rožna Dolina, 5000 Nova Gorica) was 49.3 μgL–1. The Fe (II) and Fe (III) concentra- tion amounted to 12.8 μgL–1 and 39.9 μgL–1, respectively. Such an approach opens new opportunities for monitoring the content of iron species in natural waters and sediments and provides highly sensitive chemical analysis and an accurate qualitative and quantitative characteristic of the materials under study. |
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| Keywords: | Beam deflection spectroscopy, diffusive gradients in thin-film technique, iron redox species, photothermal techniques, sediment |
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| Year of publishing: | 2019 |
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| Number of pages: | 239-246 |
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| Numbering: | 1, 2019 |
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| COBISS_ID: | 5332475  |
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| URN: | URN:SI:UNG:REP:U5VDCLUM |
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| DOI: | 10.17344/acsi.2018.4848 |
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| License: | 
This work is available under this license: Creative Commons Attribution 4.0 International |
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| Views: | 2982 |
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| Downloads: | 110 |
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| Metadata: |     |
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| Categories: | Document is not linked to any category. |
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