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Title:Taming the topology of calix[4]arene-based 2D-covalent organic frameworks : interpenetrated vs noninterpenetrated frameworks and their selective removal of cationic dyes
Authors:ID Garai, Bikash (Author)
ID Shetty, Dinesh (Author)
ID Škorjanc, Tina (Author)
ID Gándara, Felipe (Author)
ID Naleem, Nawavi (Author)
ID Varghese, Sabu (Author)
ID Sharma, Sudhir Kumar (Author)
ID Baias, Maria (Author)
ID Jagannathan, Ramesh (Author)
ID Olson, Mark Anthony (Author)
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Work type:Unknown
Typology:1.01 - Original Scientific Article
Organization:UNG - University of Nova Gorica
Abstract:A bowl-shaped calix[4]arene with its exciting host–guest chemistry is a versatile supramolecular building block for the synthesis of distinct coordination cages or metal–organic frameworks. However, its utility in the synthesis of crystalline covalent organic frameworks (COFs) remains challenging, presumably due to its conformational flexibility. Here, we report the synthesis of a periodic 2D extended organic network of calix[4]arenes joined by a linear benzidine linker via dynamic imine bonds. By tuning the interaction among neighboring calixarene units through varying the concentration in the reaction mixture, we show the selective formation of interpenetrated (CX4-BD-1) and non-interpenetrated (CX4-BD-2) frameworks. The cone-shaped calixarene moiety in the structural backbone allows for the interweaving of two neighboring layers in CX4-BD-1, making it a unique example of interpenetrated 2D layers. Due to the high negative surface charge from calixarene units, both COFs have shown high performance in charge-selective dye removal and an exceptional selectivity for cationic dyes irrespective of their molecular size. The charge distribution of the COFs and the resulting selectivity for the cationic dyes were further investigated using computational methods.
Keywords:dyes and pigments, covalent organic frameworks, adsorption, layers, chemical structure
Year of publishing:2021
Number of pages:str. 3407-3415
Numbering:Vol. 143, iss. 9
PID:20.500.12556/RUNG-6347 New window
COBISS.SI-ID:55367939 New window
ISSN on article:0002-7863
DOI:10.1021/jacs.0c12125 New window
Publication date in RUNG:16.03.2021
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Record is a part of a journal

Title:Journal of the American Chemical Society
Shortened title:J. Am. Chem. Soc.
Publisher:American Chemical Society
COBISS.SI-ID:5281029 New window