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Title:
Synthesis of efficient iron phosphide catalyst for electrocatalytic hydrogen generation
Authors:
ID
Chouki, Takwa
(Author)
ID
Lazarević, D.
(Author)
ID
Donkova, B.
(Author)
ID
Emin, Saim
(Author)
Files:
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COBISS.
Language:
English
Work type:
Unknown
Typology:
1.01 - Original Scientific Article
Organization:
UNG - University of Nova Gorica
Abstract:
A solvothermal synthesis of iron phosphide electrocatalysts using triphenylphosphine (TPP) as phosphorus precursor is presented. The synthetic protocol generates Fe2P/FeP phase at 350°C. After deposition of the catalyst onto graphite substrate heat-treatment at higher temperature was carried out. Annealing at 500°C under reductive atmosphere induced structural changes in the Fe2P/FeP samples which yielded a pure Fe2P phase. The electrocatalytic activity of the Fe2P catalyst was studied for hydrogen evolution reaction (HER) in 0.5 M H2SO4. The recorded overpotential for HER was about 130 mV vs. a reversible hydrogen electrode (RHE) at 10 mA cm−2
Keywords:
solvothermal synthesis
,
iron phosphide
,
electrocatalyst
,
hydrogen evolution
Year of publishing:
2021
Number of pages:
str. 72-77
Numbering:
Vol. 53, iss. 1
PID:
20.500.12556/RUNG-6525
COBISS.SI-ID:
62474499
UDC:
54
ISSN on article:
0861-9808
DOI:
10.34049/bcc.53.1.5323
NUK URN:
URN:SI:UNG:REP:XDTH3WMT
Publication date in RUNG:
10.05.2021
Views:
3003
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0
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Record is a part of a journal
Title:
Bulgarian chemical communications
Shortened title:
Bulg. Chem. Commun.
Publisher:
Bulgarian Academy of Sciences, Bulgarian chemical society
ISSN:
0861-9808
COBISS.SI-ID:
36418309
Document is financed by a project
Funder:
ARRS - Slovenian Research Agency
Project number:
NI-0002
Name:
A MULTIDISCIPLINARY APPROACH TO THE TREATMENT AND APPLICATION OF WASTE WATER TO AGRICULTURE
Secondary language
Language:
Undetermined
Title:
Synthesis of efficient iron phosphide catalyst for electrocatalytic hydrogen generation
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