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Title:Correlation between FeCl2 electrolyte conductivity and electrolysis efficiency
Authors:ID Luin, Uroš, Materials Research Laboratory, University of Nova Gorica, Vipavska 11c 5270 Ajdovščina, Slovenia (Author)
ID Valant, Matjaž, Materials Research Laboratory, University of Nova Gorica, Vipavska 11c 5270 Ajdovščina, Slovenia (Author)
ID Arčon, Iztok, Department of Low and Medium Energy Physics, J. Stefan Institute, Jamova 39, SI-1001 Ljubljana, Slovenia (Author)
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Typology:1.12 - Published Scientific Conference Contribution Abstract
Organization:UNG - University of Nova Gorica
Abstract:The electrolysis efficiency is an important aspect of the Power-to-Solid energy storage technology (EST) based on the iron chloride electrochemical cycle [1]. This cycle employs an aqueous FeCl2 catholyte solution for the electro-reduction of iron. The metal iron deposits on the cathode. The energy is stored as a difference in the redox potential of iron species. Hydrogen, as an energy carrier, is released on demand over a fully controlled hydrogen evolution reaction between metallic Fe0 and HCl (aq) [1]. Due to these characteristics, the cycle is suitable for long-term high-capacity and high-power energy storage. In a previous work [2] we revealed that the electrolyte conductivity linearly increases with temperature. Contrary, the correlation between the electrolyte concentration and efficiency is not so straightforward. Unexpectedly small efficiency variations were found between 1 and 2.5 mol dm-3 FeCl2 (aq) followed by an abrupt efficiency drop at higher concentrations. To explain the behavior of the observed trends and elucidate the role of FeCl2 (aq) complex ionic species we performed in situ X-ray absorption studies. We made a dedicated experimental setup, consisting of a tubular oven and PMMA liquid absorption cell, and performed the measurements at the DESY synchrotron P65 beamline. The XAS investigation covered XANES and EXAFS analyses of FeCl2 (aq) at different concentrations (1 - 4 molL-1) and temperatures (25 - 80 °C). We found that at low temperature and low FeCl2 concentration the octahedral first coordination sphere around Fe is occupied by one Cl ion at a distance of 2.33 (±0.02) Å and five water molecules at a distance of 2.095 (±0.005) Å [3]. The structure of the ionic complex gradually changes with an increase in temperature and/or concentration. The apical water molecule is substituted by a chlorine ion to yield a neutral Fe[Cl2(H2O)4]0. The transition from the single charged Fe[Cl(H2O)5]+ to the neutral Fe[Cl2(H2O)4]0 causes a significant drop in the solution conductivity, which well correlates with the existing conductivity models [3]. [1] M. Valant, “Procedure for electric energy storage in solid matter. United States Patent and Trademark Office. Patent No. US20200308715,” Patent No. US20200308715, 2021. [2] U. Luin and M. Valant, “Electrolysis energy efficiency of highly concentrated FeCl2 solutions for power-to-solid energy storage technology,” J. Solid State Electrochem., vol. 26, no. 4, pp. 929–938, Apr. 2022, doi: 10.1007/S10008-022-05132-Y. [3] U. Luin, I. Arčon, and M. Valant, “Structure and Population of Complex Ionic Species in FeCl2 Aqueous Solution by X-ray Absorption Spectroscopy,” Molecules, vol. 27, no. 3, 2022, doi: 10.3390/molecules27030642.
Keywords:Iron chloride electrochemical cycle, Power-to-Solid energy storage, XANES, EXAFS, electrical conductivity, electrolyte complex ionic species structure and population
Year of publishing:2022
PID:20.500.12556/RUNG-7626 New window
COBISS.SI-ID:122971139 New window
Publication date in RUNG:26.09.2022
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Title:SLOVENSKI kemijski dnevi (2022 ; Portorož) Slovenski kemijski dnevi 2022 [Elektronski vir] = 28th Annual Meeting of the Slovenian Chemical Society : zbornik povzetkov = book of abstracts : 21.-23. september 2022, Portorož, Portorose, Slovenija / [uredili Albin Pintar ... et al.]. - Ljubljana : Slovensko kemijsko društvo, 2022 COBISS.SI-ID 120198659
Editors:Pintar Albin
Place of publishing:Ljubljana
Publisher:Slovensko kemijsko društvo
Year of publishing:2022
Conference organizer:Slovensko Kemijsko Društvo