| Title: | Crystallizing covalent organic frameworks from metal organic framework through chemical induced-phase engineering |
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| Authors: | ID Khayum Mohammed, Abdul (Author)
ID Gaber, Safa (Author)
ID Raya, Jesus (Author)
ID Škorjanc, Tina (Author)
ID Elmerhi, Nada (Author)
ID Stephen, Sasi (Author)
ID Pena-Sánchez, Pilar (Author)
ID Gándara, Felipe (Author)
ID Hinder, Steven (Author)
ID Baker, Mark A. (Author)
ID Polychronopoulou, Kyriaki (Author)
ID Shetty, Dinesh (Author) |
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| Files: |  https://www.nature.com/articles/s41598-023-46573-3
 s41598-023-46573-3.pdf (3,64 MB)
MD5: 43250986A83C6994C1C51874FD645EA6
https://www.nature.com/articles/s41598-023-46573-3
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| Language: | English |
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| Work type: | Unknown |
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| Typology: | 1.01 - Original Scientific Article |
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| Organization: | UNG - University of Nova Gorica
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| Abstract: | The ordered porous frameworks like MOFs and COFs are generally constructed using the monomers through distinctive metal-coordinated and covalent linkages. Meanwhile, the inter-structural transition between each class of these porous materials is an under-explored research area. However, such altered frameworks are expected to have exciting features compared to their pristine versions. Herein, we have demonstrated a chemical-induction phase-engineering strategy to transform a two dimensional conjugated Cu-based SA-MOF (Cu-Tp) into 2D-COFs (Cu-TpCOFs). The structural phase transition offered in-situ pore size engineering from 1.1 nm to 1.5–2.0 nm. Moreover, the Cu-TpCOFs showed uniform and low percentage-doped (~ 1–1.5%) metal distribution and improved crystallinity, porosity, and stability compared to the parent Cu-Tp MOF. The construction of a framework from another framework with new linkages opens interesting opportunities for phase-engineering. |
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| Keywords: | metal organic framework, covalent organic framework, phase engineering, chemical transformation, porous materials |
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| Publication date: | 01.01.2023 |
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| Year of publishing: | 2023 |
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| Number of pages: | str. 1-7 |
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| Numbering: | Vol. 13, article no. ǂ19443 |
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| PID: | 20.500.12556/RUNG-8621-0d201bce-5b61-5f43-f9ae-525909bf51b0  |
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| COBISS.SI-ID: | 171577091 |
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| UDC: | 54 |
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| ISSN on article: | 2045-2322 |
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| DOI: | 10.1038/s41598-023-46573-3 |
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| NUK URN: | URN:SI:UNG:REP:BA8JVMRY |
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| Publication date in RUNG: | 10.11.2023 |
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| Views: | 2971 |
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| Downloads: | 7 |
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